Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Textbook Question
Chapter 20, Problem 24P
Show how you might synthesize each of the following compounds from 1-butanol:
(a) Butylamine (free of 2° and 3°
(b) Pentylamine
(c) Propylamine
(d) Butylmethylamine
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and
dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a
resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if
applicable).
ード
M
4-
b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible
isomers and their corresponding point groups. Use the point groups to determine if the complexes have
resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if
applicable). The number of complex sketches below is not necessarily indicative of the number of isomers.
4-
4-
☐☐☐
c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible
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Show work. don't give Ai generated solution
Chapter 20 Solutions
Organic Chemistry
Ch. 20 - Prob. 1PPCh. 20 - Prob. 2PPCh. 20 - Practice Problem 20.3
Write a mechanism that...Ch. 20 - Prob. 4PPCh. 20 - PRACTICE PROBLEM 20.5 Outline a preparation of...Ch. 20 - Prob. 6PPCh. 20 - Prob. 7PPCh. 20 - Prob. 8PPCh. 20 - Prob. 9PPCh. 20 - Prob. 10PP
Ch. 20 - Practice Problem 20.11 In the preceding examples...Ch. 20 - Prob. 12PPCh. 20 - Prob. 13PPCh. 20 - Practice Problem 20.14
Outline a synthesis of...Ch. 20 - Prob. 15PPCh. 20 - Prob. 16PPCh. 20 - Prob. 17PPCh. 20 - Prob. 18PPCh. 20 - Prob. 19PCh. 20 - 20.20 Give common or systematic names for each of...Ch. 20 - Which is the most basic nitrogen in each compound?...Ch. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Show how you might synthesize each of the...Ch. 20 - Prob. 25PCh. 20 - 20.26 Provide the major organic product from each...Ch. 20 - Prob. 27PCh. 20 - 20.28 What products would you expect to be formed...Ch. 20 - Prob. 29PCh. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Write equations for simple chemical rests or state...Ch. 20 - Prob. 33PCh. 20 - Explain the following, including mention of key...Ch. 20 - 20.35 Provide a detailed mechanism for each of the...Ch. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - Prob. 39PCh. 20 - 20.40 Give structures for compounds R-W:
Ch. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Diethylpropion (shown here) is a compound used in...Ch. 20 - Prob. 44PCh. 20 - 20.45 Compound W is soluble in dilute aqueous HCI...Ch. 20 - 20.46 Propose structures for compounds X, Y, and...Ch. 20 - Compound A(C10H15N) is soluble in dilute HCI. The...Ch. 20 - Prob. 48PCh. 20 - Prob. 49PCh. 20 - For each of the following, identify the product...Ch. 20 - 20.51 Develop a synthesis for the following...Ch. 20 - 20.52 When phenyl isochiocyanatc, , is reduced...Ch. 20 - Prob. 53PCh. 20 - 20.54 Propose a mechanism that can explain the...Ch. 20 - When acetone is treated with anhydrous ammonia in...Ch. 20 - Prob. 56P
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