
Interpretation:
The synthesis of
Concept introduction:
舧 Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.
舧 Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.
舧 Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction.
舧 Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
舧 Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.
舧 The reaction in which hydrogen is added to the compound in the presence of catalyst is known as hydrogenation.
舧 The number of moles of hydrogen absorbed will be equal to the number of double bonds.
舧 The reaction in which a halide group is removed to form an alkene is called dehydrohalogenation.
舧 This reaction in which
舧 Acetylation refers to the process of introducing an acetyl group into a compound. A reaction involving te replacement of the hydrogen atom of a hydroxyl or amine group with an acetyl group. Acetic anhydride is commonly used as an acetylating agent.
舧 Piperidine is a heterocyclic amine containing six membered rings, which contains five methyl groups and one nitrogen atom.
舧 Nitrous acid
舧 Nitrous acid is used to make diazonium salts from amines.
舧 The reaction of primary aryl amine with nitrous acid gives arenediazonium salt.
舧 The nitro compounds formed by direct nitration reaction undergo reduction to give primary aryl amine.
舧 The diazonium group is easily replaced by another group.
舧 In Sandmeyer reaction, arenediazonium salt reacts with cuprous bromide, cuprous cyanide, and cuprous chloride, and the replacement of diazonium group by
舧 The replacement of diazonium group by
舧 The replacement of diazonium group by

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Chapter 20 Solutions
Organic Chemistry
- Calculate the pH and the pOH of each of the following solutions at 25 °C for which the substances ionize completely: (a) 0.000259 M HClO4arrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardDetermine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃arrow_forward
- A. Draw the structure of each of the following alcohols. Then draw and name the product you would expect to produce by the oxidation of each. a. 4-Methyl-2-heptanol b. 3,4-Dimethyl-1-pentanol c. 4-Ethyl-2-heptanol d. 5,7-Dichloro-3-heptanolarrow_forwardWhat is the pH of a 1.0 L buffer made with 0.300 mol of HF (Ka = 6.8 × 10⁻⁴) and 0.200 mol of NaF to which 0.160 mol of NaOH were added?arrow_forwardCan I please get help with this.arrow_forward
- Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. N₂H₅ClO₄arrow_forwardPlease help me with identifying these.arrow_forwardCan I please get help with this?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

