
Interpretation:
The synthesis of
Concept introduction:
舧 Electrophiles are electron-deficient species, which has positive or partially positive charge. Lewis acids are electrophiles, which accept electron pair.
舧 Nucleophiles are electron-rich species, which has negative or partially negative charge. Lewis bases are nucleophiles, which donate electron pair.
舧 Substitution reaction: A reaction in which one of the hydrogen atoms of a hydrocarbon or a functional group is substituted by any other functional group is called substitution reaction.
舧 Elimination reaction: A reaction in which two substituent groups are detached and a double bond is formed is called elimination reaction.
舧 Addition reaction: It is the reaction in which unsaturated bonds are converted to saturated molecules by the addition of molecules.
舧 The reaction in which hydrogen is added to the compound in the presence of catalyst is known as hydrogenation.
舧 The number of moles of hydrogen absorbed will be equal to the number of double bonds.
舧 The reaction in which a halide group is removed to form an alkene is called dehydrohalogenation.
舧 This reaction in which
舧 Acetylation refers to the process of introducing an acetyl group into a compound. A reaction involving te replacement of the hydrogen atom of a hydroxyl or amine group with an acetyl group. Acetic anhydride is commonly used as an acetylating agent.
舧 Piperidine is a heterocyclic amine containing six membered rings, which contains five methyl groups and one nitrogen atom.
舧 Nitrous acid
舧 Nitrous acid is used to make diazonium salts from amines.
舧 The reaction of primary aryl amine with nitrous acid gives arenediazonium salt.
舧 The nitro compounds formed by direct nitration reaction undergo reduction to give primary aryl amine.
舧 The diazonium group is easily replaced by another group.
舧 In Sandmeyer reaction, arenediazonium salt reacts with cuprous bromide, cuprous cyanide, and cuprous chloride, and the replacement of diazonium group by
舧 The replacement of diazonium group by
舧 The replacement of diazonium group by

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Chapter 20 Solutions
Organic Chemistry
- Tartaric acid (C4H6O6) is a diprotic weak acid. A sample of 875 mg tartaric acid are dissolved in 100 mL water and titrated with 0.994 M NaOH. How many mL of NaOH are needed to reach the first equivalence point? How many mL of NaOH are needed to reach the second equivalence point?arrow_forwardIncluding activity, calculate the solubility of Pb(IO3)2 in a matrix of 0.020 M Mg(NO3)2.arrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M KBr.arrow_forward
- Including activity, calculate the pH of a 0.010 M HCl solution with an ionic strength of 0.10 M.arrow_forwardCan I please get the graph 1: Concentration vs. Density?arrow_forwardOrder the following series of compounds from highest to lowest reactivity to electrophilic aromatic substitution, explaining your answer: 2-nitrophenol, p-Toluidine, N-(4-methylphenyl)acetamide, 4-methylbenzonitrile, 4-(trifluoromethyl)benzonitrile.arrow_forward
- Ordene la siguiente serie de compuestos de mayor a menor reactividad a la sustitución aromática electrofílica, explicando su respuesta: ácido bencenosulfónico, fluorobenceno, etilbenceno, clorobenceno, terc-butilbenceno, acetofenona.arrow_forwardCan I please get all final concentrations please!arrow_forwardState the detailed mechanism of the reaction of benzene with isopropanol in sulfuric acid.arrow_forward
- Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction. For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 -> NO2 + NO3_(K1) NO2 + NO3 →> N2O5 (k-1) → NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Give the expression for the acceptable rate. (A). d[N₂O] dt = -1 2k,k₂[N205] k₁+k₂ d[N₂O5] (B). dt =-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³ (C). d[N₂O] dt =-k₁[N₂O] + k₁[N205] - K3 [NO] [N205] (D). d[N2O5] =-k₁[NO] - K3[NO] [N₂05] dtarrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

