General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 20, Problem 20.27P
Interpretation Introduction

(a)

Interpretation:

The structure of an L- aldopentose needs to be drawn.

Concept introduction:

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. Aldopentose is a five-carbon aldehyde sugar.

Expert Solution
Check Mark

Answer to Problem 20.27P

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  1

Explanation of Solution

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. The absolute configuration of a molecule can be explained using D and L configuration. In D- sugars, the OH group on the bottom chiral center points to the right while in L- sugars, the OH group on the bottom chiral center points to the left. Aldopentose is a five-carbon aldehyde sugar. Xylose, Arabinose and Ribose are few examples.

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  2

Interpretation Introduction

(b)

Interpretation:

The structure of a D- tetrose needs to be drawn.

Concept introduction:

Sugar molecules can name as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. Aldotetrose is a four-carbon aldehyde sugar.

Expert Solution
Check Mark

Answer to Problem 20.27P

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  3

Explanation of Solution

Sugar molecules can be named as D or L sugars according to their most oxidized carbon at the top of the Fisher projection. The absolute configuration of a molecule can be explained using D and L configuration. In D- sugars, the OH group on the bottom chiral center points to the right while if L-sugars, the OH group on the bottom chiral center points to the left. Aldotetrose is a four-carbon aldehyde sugar.

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  4

Interpretation Introduction

(c)

Interpretation:

The structure of a five-carbon alditol needs to be drawn.

Concept introduction:

Alditols are polyols. Alditols can be produced by reducing an aldehyde or a ketone group in a monosaccharide.

Expert Solution
Check Mark

Answer to Problem 20.27P

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  5

Explanation of Solution

Alditols are polyols. Alditols can be produced by reducing an aldehyde or a ketone group in a monosaccharide. In this reduction process, an aldehyde group or a ketone group converts into −CH2OH group. Xylitol is an example of an alditol.

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  6

For an example:

  General, Organic, & Biological Chemistry, Chapter 20, Problem 20.27P , additional homework tip  7

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Chapter 20 Solutions

General, Organic, & Biological Chemistry

Ch. 20.3 - Prob. 20.11PCh. 20.3 - Prob. 20.12PCh. 20.4 - Prob. 20.13PCh. 20.4 - Prob. 20.14PCh. 20.4 - Prob. 20.15PCh. 20.4 - Prob. 20.16PCh. 20.4 - Prob. 20.17PCh. 20.4 - Prob. 20.18PCh. 20.5 - Lactose contains both an acetal and a hemiacetal....Ch. 20.5 - Prob. 20.20PCh. 20.5 - Prob. 20.21PCh. 20.6 - Prob. 20.22PCh. 20.6 - Prob. 20.23PCh. 20.7 - Prob. 20.24PCh. 20.7 - Prob. 20.25PCh. 20.8 - Prob. 20.26PCh. 20 - Prob. 20.27PCh. 20 - Prob. 20.28PCh. 20 - Prob. 20.29PCh. 20 - Prob. 20.30PCh. 20 - Prob. 20.31PCh. 20 - Prob. 20.32PCh. 20 - Prob. 20.33PCh. 20 - Prob. 20.34PCh. 20 - Prob. 20.35PCh. 20 - Prob. 20.36PCh. 20 - Prob. 20.37PCh. 20 - Prob. 20.38PCh. 20 - Prob. 20.39PCh. 20 - Prob. 20.40PCh. 20 - Prob. 20.41PCh. 20 - Prob. 20.42PCh. 20 - Prob. 20.43PCh. 20 - Prob. 20.44PCh. 20 - Prob. 20.45PCh. 20 - Prob. 20.46PCh. 20 - Prob. 20.47PCh. 20 - Prob. 20.48PCh. 20 - Prob. 20.49PCh. 20 - Prob. 20.50PCh. 20 - Prob. 20.51PCh. 20 - Prob. 20.52PCh. 20 - Prob. 20.53PCh. 20 - Prob. 20.54PCh. 20 - Prob. 20.55PCh. 20 - Prob. 20.56PCh. 20 - Prob. 20.57PCh. 20 - Prob. 20.58PCh. 20 - Prob. 20.59PCh. 20 - Prob. 20.60PCh. 20 - Prob. 20.61PCh. 20 - Prob. 20.62PCh. 20 - Prob. 20.63PCh. 20 - Prob. 20.64PCh. 20 - Prob. 20.65PCh. 20 - Prob. 20.66PCh. 20 - Prob. 20.67PCh. 20 - Prob. 20.68PCh. 20 - Prob. 20.69PCh. 20 - Prob. 20.70PCh. 20 - Prob. 20.71PCh. 20 - Prob. 20.72PCh. 20 - Prob. 20.73PCh. 20 - Prob. 20.74PCh. 20 - Prob. 20.75PCh. 20 - Prob. 20.76PCh. 20 - Prob. 20.77PCh. 20 - Prob. 20.78PCh. 20 - Prob. 20.79PCh. 20 - Prob. 20.80PCh. 20 - Prob. 20.81PCh. 20 - Prob. 20.82PCh. 20 - Prob. 20.83PCh. 20 - Prob. 20.84PCh. 20 - Prob. 20.85PCh. 20 - Prob. 20.86PCh. 20 - Prob. 20.87CPCh. 20 - Prob. 20.88CP
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