Principles of General Chemistry
Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 2, Problem 2.77P

a)

Interpretation Introduction

Interpretation:The molecular formula of sodium dichromateshould be written. Also, molecular mass of sodium dichromateis to be determined.

Concept introduction:In the molecular formula, the exact number and type of constituent atoms are shown. Type of constituent atoms is represented by their atomic symbols and the number of each constituent atom is represented by right subscript of its atomic symbol. The number of each constituent in a molecule depends on its valency. The valency of an element is calculated from its electronic configuration, whichis how many electrons it can lose or gain to attain a stable electronic configuration.

In a hypothetical molecule AxBy , ratio of the valency of A and valency of B is y:x . Molecular mass is the sum of atomic masses of all atoms in a molecule.

b)

Interpretation Introduction

Interpretation:Molecular formula of ammonium perchlorate NH4ClO4 should be given .Also.molecular mass of ammonium perchlorate NH4ClO4 is to be determined.

Concept introduction:In the molecular formula, the exact number and type of constituent atoms are shown. Type of constituent atoms is represented by their atomic symbols and the number of each constituent atom is represented by right subscript of its atomic symbol. The number of each constituent in a molecule depends on its valency. The valency of an element is calculated from its electronic configuration, which is how many electrons it can lose or gain to attain a stable electronic configuration.

In a hypothetical molecule AxBy , ratio of the valency of A and valency of B is y:x . Molecular mass is the sum of atomic masses of all atoms in a molecule.

c)

Interpretation Introduction

Interpretation:The molecular formula of magnesium nitrite trihydrate should be given. Also, molecular mass of magnesium nitrite trihydrate is to be determined.

Concept introduction:In the molecular formula, the exact number and type of constituent atoms are shown. Type of constituent atoms is represented by their atomic symbols and the number of each constituent atom is represented by right subscript of its atomic symbol. The number of each constituent in a molecule depends on its valency. The valency of an element is calculated from its electronic configuration, which is how many electrons it can lose or gain to attain a stable electronic configuration.

In a hypothetical molecule AxBy , ratio of the valency of A and valency of B is y:x . Molecular mass is the sum of atomic masses of all atoms in a molecule.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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Chapter 2 Solutions

Principles of General Chemistry

Ch. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Show, with calculations, how the following data...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Prob. 2.32PCh. 2 - Draw atomic depictions similar to those in Problem...Ch. 2 - Gallium has two naturally occurring isotopes,...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Fill in the blanks: (a) The symbol and atomic...Ch. 2 - Prob. 2.44PCh. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Given that the ions in LiF and in MgO are of...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - An ionic compound forms when calcium (Z=20) reacts...Ch. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.59PCh. 2 - Prob. 2.60PCh. 2 - Write a formula for each of the following...Ch. 2 - Prob. 2.62PCh. 2 - Give the name and formula of the compound formed...Ch. 2 - Prob. 2.64PCh. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - Prob. 2.67PCh. 2 - Prob. 2.68PCh. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - Prob. 2.73PCh. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Give the formula, name, and molecular mass of the...Ch. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - Prob. 2.83PCh. 2 - Prob. 2.84PCh. 2 - Prob. 2.85PCh. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - Prob. 2.89PCh. 2 - Scenes A— depict various types of matter on the...Ch. 2 - The scvcn most abundant ions in seawater make up...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - Prob. 2.94PCh. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - Dinitrogen monoxide (N2O;nitrousoxide) is a...Ch. 2 - Prob. 2.98PCh. 2 - Prob. 2.99PCh. 2 - Prob. 2.100PCh. 2 - A rock is 5.0% by mass fayalite (Fe2SiO4)7.0% by...Ch. 2 - The two isotopes of potassium with significant...Ch. 2 - Prob. 2.103PCh. 2 - Prob. 2.104PCh. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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