Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 2, Problem 2.30P
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The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
1. Show the steps necessary to make 2-methyl-4-nonene using a
Wittig reaction. Start with triphenylphosphine and an alkyl
halide. After that you may use any other organic or inorganic
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2. Write in the product of this reaction:
CH3
CH₂
(C6H5)₂CuLi
H₂O+
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H₂C
H3C
CH3
OH
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left into the acid on the right.
Bri
CH2
5. Write in the product of this
LiAlH4
Br
H₂C
OH
Chapter 2 Solutions
Principles of General Chemistry
Ch. 2 - What is the key difference between an element and...Ch. 2 - List two differences between a compound and a...Ch. 2 - Which of the following are pure substances?...Ch. 2 - Classify each substance in Problem 2.3 as an...Ch. 2 - Each scene below represents a mixture. Describe...Ch. 2 - To which classes of matter—element, compound,...Ch. 2 - Identify the mass law that each of the following...Ch. 2 - Prob. 2.8PCh. 2 - (a) Does the percent by mass of each element in a...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Show, with calculations, how the following data...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Prob. 2.32PCh. 2 - Draw atomic depictions similar to those in Problem...Ch. 2 - Gallium has two naturally occurring isotopes,...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Fill in the blanks: (a) The symbol and atomic...Ch. 2 - Prob. 2.44PCh. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Given that the ions in LiF and in MgO are of...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - An ionic compound forms when calcium (Z=20) reacts...Ch. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.59PCh. 2 - Prob. 2.60PCh. 2 - Write a formula for each of the following...Ch. 2 - Prob. 2.62PCh. 2 - Give the name and formula of the compound formed...Ch. 2 - Prob. 2.64PCh. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - Prob. 2.67PCh. 2 - Prob. 2.68PCh. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - Prob. 2.73PCh. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Give the formula, name, and molecular mass of the...Ch. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - Prob. 2.83PCh. 2 - Prob. 2.84PCh. 2 - Prob. 2.85PCh. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - Prob. 2.89PCh. 2 - Scenes A— depict various types of matter on the...Ch. 2 - The scvcn most abundant ions in seawater make up...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - Prob. 2.94PCh. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - Dinitrogen monoxide (N2O;nitrousoxide) is a...Ch. 2 - Prob. 2.98PCh. 2 - Prob. 2.99PCh. 2 - Prob. 2.100PCh. 2 - A rock is 5.0% by mass fayalite (Fe2SiO4)7.0% by...Ch. 2 - The two isotopes of potassium with significant...Ch. 2 - Prob. 2.103PCh. 2 - Prob. 2.104PCh. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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