Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Textbook Question
Chapter 2, Problem 2.34P
Gallium has two naturally occurring isotopes,
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Part 1. Draw monomer units of the following products and draw their reaction mechanism
1) Bakelite like polymer
Using: Resorcinol + NaOH + Formalin
2) Polyester fiber
Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol
B)pthalic anhydride + anhydrous sodium acetate + glycerol
3) Temporary cross-linked polymer
Using: 4% polyvinyl alcohol+ methyl red + 4% sodium borate
Using the table of Reactants and Products provided provide the correct letter that
corresponds with the Carboxylic acid that is formed in the reaction below.
6 M NaOH
Acid-workup
WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR
PHRASES
A)
Pool of Reagents for Part B
CI
B)
OH
C)
E)
CI
J)
racemic
F)
K)
OH
N)
OH
P)
G)
OH
D)
HO
H)
L)
M)
HO
Q)
R)
CI
A
In the table below, the exact chemical structures for Methyl salicylate can be
represented by the letter
WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR
PHRASES
CI
B)
A)
E)
Cl
racemic
F)
J)
CI
K)
N)
OH
P)
Pool of Reagents for Part B
OH
OH
G)
L)
OH
D)
HO
H)
M)
HO
Q)
R)
CI
Chapter 2 Solutions
Principles of General Chemistry
Ch. 2 - What is the key difference between an element and...Ch. 2 - List two differences between a compound and a...Ch. 2 - Which of the following are pure substances?...Ch. 2 - Classify each substance in Problem 2.3 as an...Ch. 2 - Each scene below represents a mixture. Describe...Ch. 2 - To which classes of matter—element, compound,...Ch. 2 - Identify the mass law that each of the following...Ch. 2 - Prob. 2.8PCh. 2 - (a) Does the percent by mass of each element in a...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Show, with calculations, how the following data...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Write the ZAX notation for each atomic depiction:Ch. 2 - Prob. 2.32PCh. 2 - Draw atomic depictions similar to those in Problem...Ch. 2 - Gallium has two naturally occurring isotopes,...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - Fill in the blanks: (a) The symbol and atomic...Ch. 2 - Prob. 2.44PCh. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - Given that the ions in LiF and in MgO are of...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - Prob. 2.51PCh. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - An ionic compound forms when calcium (Z=20) reacts...Ch. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - Prob. 2.59PCh. 2 - Prob. 2.60PCh. 2 - Write a formula for each of the following...Ch. 2 - Prob. 2.62PCh. 2 - Give the name and formula of the compound formed...Ch. 2 - Prob. 2.64PCh. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - Prob. 2.67PCh. 2 - Prob. 2.68PCh. 2 - Prob. 2.69PCh. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - Prob. 2.73PCh. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Give the formula, name, and molecular mass of the...Ch. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - Prob. 2.83PCh. 2 - Prob. 2.84PCh. 2 - Prob. 2.85PCh. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - Prob. 2.89PCh. 2 - Scenes A— depict various types of matter on the...Ch. 2 - The scvcn most abundant ions in seawater make up...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - Prob. 2.94PCh. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - Dinitrogen monoxide (N2O;nitrousoxide) is a...Ch. 2 - Prob. 2.98PCh. 2 - Prob. 2.99PCh. 2 - Prob. 2.100PCh. 2 - A rock is 5.0% by mass fayalite (Fe2SiO4)7.0% by...Ch. 2 - The two isotopes of potassium with significant...Ch. 2 - Prob. 2.103PCh. 2 - Prob. 2.104PCh. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
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