Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 1.SE, Problem 45AP
Tell the number of hydrogens bonded to each carbon atom in (a) the antiinfluenza agent oseltamivir, marketed as Tamiflu, and (b) the platelet aggregation inhibitor clopidogrel, marketed as Plavix. Give the molecular formula of each.
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Write condensed formulas and provide IUPAC names for the following compounds:(a) ethyl alcohol (in beverages)(b) methyl alcohol (used as a solvent, for example, in shellac)(c) ethylene glycol (antifreeze)(d) isopropyl alcohol (used in rubbing alcohol)(e) glycerine
Chapter 1 Solutions
Organic Chemistry
Ch. 1.3 - Give the ground-state electron configuration for...Ch. 1.3 - How many electrons does each of the following...Ch. 1.4 - Prob. 3PCh. 1.4 - Convert the following representation of ethane,...Ch. 1.4 - What are likely formulas for the following...Ch. 1.4 - Prob. 6PCh. 1.4 - Prob. 7PCh. 1.7 - Draw a line-bond structure for propane, CH3CH2CH3....Ch. 1.7 - Convert the following molecular model of hexane, a...Ch. 1.8 - Draw a line-bond structure for propene, CH3CH=CH2....
Ch. 1.8 - Draw a line-bond structure for 1, 3-butadiene,...Ch. 1.8 - Following is a molecular model of aspirin...Ch. 1.9 - Draw a line-bond structure for propyne, CH3C≡CH....Ch. 1.10 - Prob. 14PCh. 1.12 - Prob. 15PCh. 1.12 - Prob. 16PCh. 1.12 - The following molecular model is a representation...Ch. 1.SE - Convert each of the following molecular models...Ch. 1.SE - The following model is a representation of citric...Ch. 1.SE - The following model is a representation of...Ch. 1.SE - The following model is a representation of...Ch. 1.SE - How many valence electrons does each of the...Ch. 1.SE - Give the ground-state electron configuration for...Ch. 1.SE - Prob. 24APCh. 1.SE - Prob. 25APCh. 1.SE - Draw an electron-dot structure for acetonitrile,...Ch. 1.SE - Draw a line-bond structure for vinyl chloride,...Ch. 1.SE - Fill in any nonbonding valence electrons that are...Ch. 1.SE - Convert the following line-bond structures into...Ch. 1.SE - Convert the following molecular formulas into...Ch. 1.SE - Prob. 31APCh. 1.SE - Oxaloacetic acid, an important intermediate in...Ch. 1.SE - Prob. 33APCh. 1.SE - Potassium methoxide, KOCH3, contains both covalent...Ch. 1.SE - What is the hybridization of each carbon atom in...Ch. 1.SE - Prob. 36APCh. 1.SE - Prob. 37APCh. 1.SE - What bond angles do you expect for each of the...Ch. 1.SE - Propose structures for molecules that meet the...Ch. 1.SE - What kind of hybridization do you expect for each...Ch. 1.SE - Pyridoxal phosphate, a close relative of vitamin...Ch. 1.SE - Prob. 42APCh. 1.SE - Prob. 43APCh. 1.SE - Quetiapine, marketed as Seroquel, is a heavily...Ch. 1.SE - Tell the number of hydrogens bonded to each carbon...Ch. 1.SE - Why do you suppose no one has ever been able to...Ch. 1.SE - Allene, H2C=C=CH2, is somewhat unusual in that it...Ch. 1.SE - Allene (see Problem 1-47) is structurally related...Ch. 1.SE - Complete the electron-dot structure of caffeine,...Ch. 1.SE - Most stable organic species have tetravalent...Ch. 1.SE - A carbanion is a species that contains a...Ch. 1.SE - Divalent carbon species called carbenes are...Ch. 1.SE - There are two different substances with the...Ch. 1.SE - There are two different substances with the...Ch. 1.SE - There are two different substances with the...Ch. 1.SE - Prob. 56APCh. 1.SE - Among the most common over-the-counter drugs you...
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- (A) A researcher analyzed an unknown solid, extracted from the bark of spruce trees, to determine its percentage composition. An 11.32 mg sample was burned in a combustion apparatus. The carbon dioxide (24.87 mg) and water (5.82 mg) were collected and weighed. From the results of this analysis, Determine: (1) both empirical and molecular formulas if molar mass is 420 g/mol. (ii) How many aromatic rings can this compound contain? (iii)Give the possible chemical name and structure of this compound and hence reasons for your selection.arrow_forwardAn alkane, P, has the molecular formula, C,H.. An alkene, Q, has the molecular formula, C H,. (a) Name P and Q ánd write their full structural formulae. (b) State two differences between P and Q in terms of their structures. x'arrow_forward(a) What is meant by the term isomer ? (b) Among the four alkanes, ethane, propane, butane, and pentane, which is capable of existing in isomeric forms?arrow_forward
- Following is the structural formula of acetylsalicylic acid, better known by its common name aspirin. (a) Name the two oxygen-containing functional groups in aspirin. (b) What is the molecular formula of aspirin?arrow_forwardIndicate whether each statement is true or false: (a) Fat molecules contain amide bonds. (b) Phosphoplipids can be zwitterions. (c) Phospholipids form bilayers in water in order to have their long hydrophobic tails interact favorably with each other, leaving their polar heads to the aqueous environment.arrow_forward(26) Draw the bond-line structures and determine the chemical formulas for hexane, 1-hexene, cyclohexane, and cydohexene. Write the mathematical formula for the ratio of carbon to hydrogen for each compound to determine the pattern. (27) Like cycloalkanes, benzene can have multiple substituent groups. Sketch the skeletal structure for 3,4-dipropyl-2,5-dimethyl-1- ethylbenzene. (28) Acetylsalicylic acid, more commonly known as aspirin, is a multisubstituted benzene compound. Is the substitution a 1,2-, a 1,3-, or a 1,4-? Once you've determined the correct combination, sketch what the molecule would look like for each of the other two possible substitutions. CH3arrow_forward
- Explain each statement in terms of atomic properties:(a) Carbon engages in covalent rather than ionic bonding.(b) Carbon has four bonds in all its organic compounds.(c) Carbon forms neither stable cations, like many metals, norstable anions, like many nonmetals.(d) Carbon bonds to itself more extensively than does any otherelement.(e) Carbon forms stable multiple bondsarrow_forwardThe following compound is an intermediate in the synthesis of a gelator, which is a compound capable of self-assembling to form a gel in an organic liquid (Soft Matter 2012, 8, 5486-5492). O(CH,),,CH3 CH3(CH,),,0 H. CH,(CH,),,0 2.86a Choose the functional groups present in the given molecule. Aldehyde, amide, aromatic ring, ether Aldehyde, amide, alcohol, ether O Amine, aromatic ring, ether, ketone O Aldehyde, amide, etherarrow_forwardEnediynes are a class of compounds that include some antibiotic drugs. Draw the structure of an “enediyne” fragment that contains six carbons in a row. .arrow_forward
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