Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Question
Chapter 1.4, Problem 3P
Interpretation Introduction
Interpretation:
The tetrahedral geometry of a molecule of chloroform with molecular formula CHCl3 is to be drawn using solid, wedged and dotted lines.
Concept introduction:
To draw the structure of a tetrahedral carbon attached to four atoms or groups using solid, wedged and dotted lines certain conventions are used. The solid line is used to represent the bonds present in the plane of the paper, heavy wedged line is used to represent a bond coming out of the plane of the paper and the dotted line is used to represent a bond going back behind the plane of the paper.
To determine:
The tetrahedral geometry of a molecule of chloroform with molecular formula CHCl3 using solid, wedged and dotted lines.
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Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic.
НОН НЬ
OHd
Онс
Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left?
?
starting
material
target
If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area.
Be sure you follow the standard ALEKS rules for submitting syntheses.
+ More...
Note for advanced students: you may assume that you are using a large excess of benzene as your starting material.
C
:0
T
Add/Remove step
G
The following equations represent the formation of compound MX. What is the AH for the
electron affinity of X (g)?
X₂ (g) → 2X (g)
M (s) → M (g)
M (g)
M (g) + e-
AH = 60 kJ/mol
AH = 22 kJ/mol
X (g) + e-X (g)
M* (g) +X (g) → MX (s)
AH = 118 kJ/mol
AH = ?
AH = -190 kJ/mol
AH = -100 kJ/mol
a)
-80 kJ
b)
-30 kJ
c)
-20 kJ
d)
20 kJ
e)
156 kJ
Chapter 1 Solutions
Organic Chemistry
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