
Concept explainers
(a)
Interpretation: The radiotracer having shortest half-life using graph has to be identified.
Concept introduction: In a nuclear reaction, unstable nuclide disintegrates into stable nuclide with emission of various radiations spontaneously. It is called radioactivity of nucleus. Emission of rays like alpha, beta and gamma rays occur in the process which changes the identity of nucleus.
During a nuclear change, an element undergoes change in its
(a)

Answer to Problem 4RQ
Mo-99 has the shortest half life.
Explanation of Solution
Time needed for original or initial sample of radioactive element to decay to its half quantity or concentration is known as half-life time.
The formula to calculate half life (
Where,
For the graph shown for half life in days versus the radioactive element, it is clear that the half lives of elements are as follows:
I-131 has half life of 8 days. Similarly for Mo-99, P-32 and Xe-133 half lives are 3 days, 14 days and 5 days approximately; respectively.
So the shortest half life is for Mo-99.
(b)
Interpretation: The radiotracer having half-life equal to sum of half lives of Xe-133 and Mo-99 using graph has to be identified.
Concept introduction: In a nuclear reaction, unstable nuclide disintegrates into stable nuclide with emission of various radiations spontaneously. It is called radioactivity of nucleus. Emission of rays like alpha, beta and gamma rays occur in the process which changes the identity of nucleus.
During a nuclear change, an element undergoes change in its atomic mass or atomic number or both by emission of charged particles such as beta particle, alpha particle. Beta particle is one that has unit negative charge and alpha particle is one that has 2 unit positive charges and is equivalent to helium atom
(b)

Answer to Problem 4RQ
The radiotracer having half-life equal to sum of half lives of Xe-133 and Mo-99 is I-131.
Explanation of Solution
Time needed for original or initial sample of radioactive element to decay to its half quantity or concentration is known as half-life time.
The formula to calculate half life (
Where,
For the graph shown for half life in days versus the radioactive element, it is clear that the half lives of elements are as follows:
I-131 has half life of 8 days. Similarly for Mo-99, P-32 and Xe-133 half lives are 3 days, 14 days and 5 days approximately; respectively.
On addition of half lives of Mo-99 and Xe-133 result comes out to be 8 days which is equal to half life of I-131.
(c)
Interpretation: The radiotracer will be left in least quantity after 15 days, using graph has to be identified.
Concept introduction: In a nuclear reaction, unstable nuclide disintegrates into stable nuclide with emission of various radiations spontaneously. It is called radioactivity of nucleus. Emission of rays like alpha, beta and gamma rays occur in the process which changes the identity of nucleus.
During a nuclear change, an element undergoes change in its atomic mass or atomic number or both by emission of charged particles such as beta particle, alpha particle. Beta particle is one that has unit negative charge and alpha particle is one that has 2 unit positive charges and is equivalent to helium atom
(c)

Answer to Problem 4RQ
As per the graph, Mo-99 will be left with least quantity after 15 days.
Explanation of Solution
Time needed for original or initial sample of radioactive element to decay to its half quantity or concentration is known as half-life time.
For the graph shown for half life in days versus the radioactive element, it is clear that the half lives of elements are as follows:
I-131 has half life of 8 days. Similarly for Mo-99, P-32 and Xe-133 half lives are 3 days, 14 days and 5 days approximately; respectively.
As per the graph, Mo-99 will be left with least quantity after 15 days. This is so because its half life is 3 days, it will take 3 days to get reduced to half of its original sample. So nearly 6 days will be required to get consumed nearly full.
(d)
Interpretation: The radiotracer will be left in greatest quantity after 15 days, using graph has to be identified.
Concept introduction: In a nuclear reaction, unstable nuclide disintegrates into stable nuclide with emission of various radiations spontaneously. It is called radioactivity of nucleus. Emission of rays like alpha, beta and gamma rays occur in the process which changes the identity of nucleus.
During a nuclear change, an element undergoes change in its atomic mass or atomic number or both by emission of charged particles such as beta particle, alpha particle. Beta particle is one that has unit negative charge and alpha particle is one that has 2 unit positive charges and is equivalent to helium atom
(d)

Answer to Problem 4RQ
As per the graph, P-32 will be left with greatest quantity after 15 days.
Explanation of Solution
Time needed for original or initial sample of radioactive element to decay to its half quantity or concentration is known as half-life time.
For the graph shown for half life in days versus the radioactive element, it is clear that the half lives of elements are as follows:
I-131 has half life of 8 days. Similarly for Mo-99, P-32 and Xe-133 half lives are 3 days, 14 days and 5 days approximately; respectively.
As per the graph, P-32 will be left in greatest quantity after 15 days. This is so because its half life is 14 days approximately; it will take 14 days to get reduced to half of its original sample. So nearly 28 days more will be required to get consumed nearly full. Whereas I-131, Xe-133 and Mo-99 will require 16 days, 10 days and 6 days to consumed nearly completely respectively.
Chapter 19 Solutions
World of Chemistry
- Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution, respectively. F CI Br | Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to have a reasonable yield of product. NH2 Br Br Br OH Brarrow_forwardQ7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability. a) H₂O, OH, CH3COOT b) NH3, H₂O, H₂Sarrow_forwardQ8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution reaction with CN as the nucleophile. Br A B NH2 LL F C D OH CI LLI E Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d). a) H "Cl D + -OCH 3 Page 3 of 5arrow_forward
- Q10: (a) Propose a synthesis of C from A. (b) Propose a synthesis of C from B. Br Br ...\SCH 3 A B Carrow_forward9: Complete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forwardComplete the missing entities for following reactions (e.g., major product(s), reactants, and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for reactions a) to d).arrow_forward
- QUESTION 3: Provide the synthetic steps that convert the starting material into the product (no mechanism required). HO OH NH CH3 multiple steps 요요 H3Carrow_forwardQ6: Predict the effect of the changes given on the rate of the reaction below. CH3OH CH3Cl + NaOCH3 → CH3OCH3 + NaCl a) Change the substrate from CH3CI to CH31: b) Change the nucleophile from NaOCH 3 to NaSCH3: c) Change the substrate from CH3CI to (CH3)2CHCI: d) Change the solvent from CH3OH to DMSO.arrow_forwardQ3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2 reaction rate. a) CI Cl فيكم H3C-Cl A B C D Br Br b) A B C Br H3C-Br Darrow_forward
- Q2: Group these solvents into either protic solvents or aprotic solvents. Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3), CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OHarrow_forwardSuppose the rate of evaporation in a hot, dry region is 1.76 meters per year, and the seawater there has a salinity of 35 ‰. Assuming a 93% yield, how much salt (NaCl) can be harvested each year from 1 km2 of solar evaporation ponds that use this seawater as a source?arrow_forwardhelparrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





