Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 19, Problem 19.24P
Interpretation Introduction

(a)

Interpretation:

The cis/trans ratio refers to in permethrin is to be predicted.

Concept Introduction:

Permethrin is a synthetic insecticide containing ester group. They are used in commercial clothing and agricultural products. In cis-isomer, the atom or groups linked to the ring are on the same side of the ring or double bond. In trans-isomer, the atom or groups linked to a ring are on the opposite sides of the ring or double bond.

Interpretation Introduction

(b)

Interpretation:

The (+/) designation in cis / trans ratio refers to in permethrin is to be predicted.

Concept Introduction:

Permethrin is a synthetic insecticide containing ester group. They are used in commercial clothing and agricultural products. Racemic mixture is a mixture of enantiomers in equal amounts. It is optically inactive.

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• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak
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