N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized. Concept Introduction: Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond. The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine: The hydrolysis of amide so formed can give back the carboxylic acid and amine.

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Answer 1

Question

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

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Answer 2

Question

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

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Answer 3

Question

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

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Answer 4

Question

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

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Answer 5

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

Answer 6

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

Answer 7

Chapter 19, Problem 19.43P

Interpretation Introduction

Interpretation:

N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents. The acid and amine need to be identified from which DEET is synthesized.

Concept Introduction:

Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.

The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:

The hydrolysis of amide so formed can give back the carboxylic acid and amine.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 19.1 - Prob. 19.1P Ch. 19.4 - Problem 19-2 Complete the equation for each...Ch. 19.4 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Write the IUPAC name for each compound.Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - 0 Complete the equations for these reactions.

Solution Summary: The author explains that N, N-diethyl m-toluamide (DEET) is the active ingredient in several common insect repellents.

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Chapter 19 Solutions