(a)
Interpretation:
The
Concept Introduction:
Amides are formed by a reaction with a carboxylic acid and an amine which are the
The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:
The hydrolysis of amide so formed can give back the carboxylic acid and amine.
(b)
Interpretation:
The carboxylic acid and amine or ammonia needs to be identified from which each amide be synthesized.
Concept Introduction:
Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.
The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:
The hydrolysis of amide so formed can give back the carboxylic acid and amine.
(c)
Interpretation:
The carboxylic acid and amine or ammonia needs to be identified from which each amide be synthesized.
Concept Introduction:
Amides are formed by a reaction with a carboxylic acid and an amine which are the functional groups. This results in the formation of amide bond, in which OH group of carboxylic acid reacts with one of the H in amine group and CO-NH bond is formed. This bond is known as an amide bond.
The mechanism for formation of an amide is as follows taking example of propanoic acid and ethylamine:
The hydrolysis of amide so formed can give back the carboxylic acid and amine.
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Chapter 19 Solutions
Introduction to General, Organic and Biochemistry
- Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OHarrow_forwardDefine the simplest method to synthesize an amine ?arrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forward
- Give each of the following amines an IUPAC name. a. b. c.arrow_forwardQuestion -S1arrow_forwardThe amines are organic weak bases which are nitrogen-containing. In the early days of organic chemistry, basic amines derived from natural sources were known as “vegetable alkali”, but they are now referred to as alkaloids. The study of alkaloids provided much of the growth of organic chemistry, phytochemistry and natural products chemistry. It remains a fascinating area of research. Please search for one naturally occurring alkaloid and provide the following: Name of the alkaloid and show its structure. Identify using arrows the polar bonds in the structure Species from where it was isolated What was the use of this alkaloid in plants (if any)? What are the pharmacological, medicinal, or environmental uses or applications of this alkaloid (if any)?arrow_forward
- Using the data in Appendix C, determine which of the following bases is strong enough to deprotonate acetonitrile (CH3CN), so that equilibrium favors the products: (a) NaH; (b) Na2CO3; (c) NaOH; (d) NaNH2; (e) NaHCO3.arrow_forwardFeatures of the structure of imino acids. Formation of amides from amino acids.arrow_forwardWhen hexanoic acid (a carboxlic acid) is heated, a reaction takes place that generates water (which must be removed) and a non-acidic product. What is the product? carboxylate carboxylic acid anhydride ester amide lies! all lies! no reaction will take place!arrow_forward
- 3arrow_forwardCan you help to resolve this?arrow_forward11. Write the chemical reaction for the acid hydrolysis of each amide sample. Include the 유 condensed structural formulas of the reactants and products. 11 CH3-C-NH₂ +H20+HCI CH3-C-OH + NH4+ CI- ACETAMIDE SO -NH2 +H20 T → 0 COOH + NH 3 11arrow_forward
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