Indicate the products obtained when chlorobenzene acid reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.
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Indicate the products obtained when chlorobenzene acid reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.
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- Several diamines are building blocks for the synthesis of pharmaceuticals and agro-chemicals. Show how both 1,3-propanediamine and 1,4-butanediamine can be prepared from acrylonitrile.When 2-pentene is treated with Cl2 in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages).Draw the structural formula of the enol formed in each alkyne hydration reaction; then draw the structural formula of the carbonyl compound with which each enol is in equilibrium
- Provide the IUPAC name of the product formed from the following reaction. If no reaction is expected, write NR Br Ag₂O NHẠCHWhat reactions and reagents can be used to make phenol from benzene if electrophilic aromatic substitution reactions are excluded and benzene is the only source of carbon?Draw the structural formula of the enol formed in each alkyne hydration reaction; then draw the structural formula of the carbonyl compound with which each enol is in equilibrium
- Claisen condensation between diethyl phthalate and ethyl acetate followed by saponifi- cation, acidification, and decarboxylation forms a diketone, C,H,O,. COOEt 1. EtO Na+ HCI, H,O B NaOH, H,O + CH3COOEt C,H,O2 2. НС, Н,О heat heat COOEt Diethyl phthalate Ethyl acetate Propose structural formulas for compounds A and B and the diketone.Prepare the following compounds starting from benzaldehyde and the appropriate ketone. Provide reactions for preparing the ketones starting from aromatic hydrocarbon compounds.When aniline undergoes addition to an electrophile, the carbocation intermediate has a variety of resonance structures. Complete the scheme below showing the conversion between resonance structures. CI H CI H + H. H i The electrons of the benzene ring attack the activated chlorine atom. H
- An important step in one synthesis of carboxylic acids is the deprotonation of diethyl malonate and its alkyl-substituted derivative: Base CH;CH2O OCH,CH3 CH;CH,0 OCH2CH3 H2 Diethyl malonate Base CH;CH,0 °C `OCH,CH3 CH;CH,O OCH,CH3 R Alkyl substituted diethyl malonate NaOH can deprotonate diethyl malonate effectively, but NaOC(CH3)3 is typically used to deprotonate the alkyl-substituted derivative. Explain why.helpDraw the structure(s) of the major organic product(s) of the following reaction. Draw a structural formula for the enol form of the carbonyl compound below.