d). e). f). g). α= H2 catalytic Pd/C CH3CH2OH (1) Hg(OAc)2, CH3CH₂OH (2) NaBH4 Br2 Zn H₂O Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each) a). b). c). (E)-3-phenylprop-2-en-1-ol excess H2 catalytic Pd/C CH3CH2OH cat. OsO4, NMO CH2Cl2 BH3 THF H2O2, NaOH H3C HO

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 46CTQ
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Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any.

If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers).

If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products.

If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)

d).
e).
f).
g).
α=
H2
catalytic Pd/C
CH3CH2OH
(1) Hg(OAc)2, CH3CH₂OH
(2) NaBH4
Br2
Zn
H₂O
Transcribed Image Text:d). e). f). g). α= H2 catalytic Pd/C CH3CH2OH (1) Hg(OAc)2, CH3CH₂OH (2) NaBH4 Br2 Zn H₂O
Identify the missing starting materials/ reagents/ products in the following reactions.
Show the stereochemistry clearly in the structures, if any.
If there is a major product, draw the structures of the major product with
stereochemistry clearly indicated where applicable. Show only the diastereomers (you
do not have to draw the pairs of enantiomers).
If you believe that multiple products are formed in approximately equal amounts (hence
neither is the major product), draw the structures of the products, and show the detailed
mechanism of these reactions to justify the formation of the multiple products.
If you believe no product is formed, explain why briefly. (6 mark for each, except f and
g, which are 10 mark each)
a).
b).
c).
(E)-3-phenylprop-2-en-1-ol
excess H2
catalytic Pd/C
CH3CH2OH
cat. OsO4, NMO
CH2Cl2
BH3
THF
H2O2, NaOH
H3C
HO
Transcribed Image Text:Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any. If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers). If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products. If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each) a). b). c). (E)-3-phenylprop-2-en-1-ol excess H2 catalytic Pd/C CH3CH2OH cat. OsO4, NMO CH2Cl2 BH3 THF H2O2, NaOH H3C HO
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