Answered: 2. Construct Lewis-dot structures, and… | bartleby

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter9: Covalent Bonding: Orbitals

Section: Chapter Questions

Problem 3RQ: Describe the bonding in H2S, CH4, H2CO and HCN using the localized electron model.

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Question

2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below.
a) SiF5
(4 points)
b) IOF4
(4 points)

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(a) Draw the valid Lewis structure, identify the (b) molecular group geometry, (c) electron group geometry, (d) polarity of the bonds, (e) over-all polarity, (f) number of lone pairs, and (g) number of bonding pairs. 1. XeO2F2 (neutron diffraction experiment by Peterson, Willett and Huston. showed that F-Xe-F bond angle is 180o)
A) Explain why BrF4 with a negative charge on top is square planar, whereas BF4 with negative charge on top is tetrahedral? B) How could you expect H_X_H bond to vary in the series H2O , H2Se? Explain your answer
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IX) By writing the appropriate electron configurations and orbital box diagrams briefly EXPLAIN in your own words each one of the following questions: a) The bond length of the Br2 molecule is 2.28 Å, while the bond length of the compound KBr is 3.34 Å. The radius of K✶ is 1.52 Å. Determine the atomic radius in Å of the bromine atom and of the bromide ion. Br = Br b) Explain why there is a large difference in the atomic sizes or radius of the two (Br and Br). T
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1A2: Define electron pair domain (EPD), count EPDS on building blocks, and use EPD knowledge to determine 3D geometry and bond angles of a tetrahedral, trigonal planar, linear building block. For the indicated atoms (look for the arrows) in each of the given structures: (a) state how many EPDs are present; (b) Label tetrahedral atoms with "TET," trigonal planar atoms with "TP," and linear atoms with "LIN;" (c) Identify one (1) indicated atom in each structure for which resonance structures bring a change in the number of EPDs from 4++3/3+4 or 3+2/2+3. A resonance structure must be reported to justify your reported EPD changes. H₂C CH3 --С HO 1 Br -CH3 CH3 CI H₂C N CH3 CH3 он о

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