Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter1: Matter, Energy, And Measurement
Section: Chapter Questions
Problem 1.78P: 1-78 The kinetic energy possessed by an object with a mass of 1 g moving with a velocity of 1 cm/s...
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Transcribed Image Text:AE>AE₁ (Y/N)
AE=AE₁ (Y/N)
AE<AE₁ (Y/N)
2. HOMO and LUMO energy gap (AE) of diene and dienophile determine how easily the diene
and dienophile pair react in the Diels-Alder reaction. Please draw lines depicting HOMO and
LUMO orbital energy that are higher, lower, and equal in reference to simple butadiene and
ethylene and indicate whether each AE is smaller and larger than butadiene and ethylene pair.
OMe
OMe
SMe
SMe
energy
( +1 (
OMe
+
+
||
SMe
OMe
+
+
a
Diene Dienophile Diene Dienophile
HOMO LUMO
HOMO LUMO
b
Diene Dienophile
HOMO LUMO
C
Diene Dienophile
HOMO LUMO
d
Diene Dienophile
HOMO LUMO
e
Diene Dienophile
HOMO LUMO
AE1
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