Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Question
Chapter 18, Problem 18.56E
Interpretation Introduction
Interpretation:
The compound that serves as a starting material for prostaglandins synthesis is to be stated.
Concept introduction:
Prostaglandins belong to the physiologically active lipids known as eicosanoids. They are cyclic compounds that are synthesized in the human body. They are synthesized by
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 18 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 18 - What is the basis for deciding if a substance is a...Ch. 18 - List two major functions of lipids in the human...Ch. 18 - What functional group is common to all...Ch. 18 - Prob. 18.4ECh. 18 - Prob. 18.5ECh. 18 - Describe four structural characteristics exhibited...Ch. 18 - Describe the structure of a micelle formed by the...Ch. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Explain why the melting points of unsaturated...
Ch. 18 - What structural feature of a fatty acid is...Ch. 18 - How are fats and oils structurally similar? How...Ch. 18 - From Figure 18.7, arrange the following substances...Ch. 18 - Draw the structure of a triglyceride that contains...Ch. 18 - Prob. 18.15ECh. 18 - The percentage of fatty acid composition of two...Ch. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Why is the hydrogenation of vegetable oils of...Ch. 18 - Prob. 18.21ECh. 18 - Write reactions to show how each of the following...Ch. 18 - Draw the structure of a wax formed from oleic acid...Ch. 18 - Prob. 18.24ECh. 18 - Draw the structure of a wax formed from stearic...Ch. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Draw the general block diagram structure of a...Ch. 18 - Draw the structure of a phosphoglyceride...Ch. 18 - Describe two biological roles served by the...Ch. 18 - Prob. 18.31ECh. 18 - What is the structural difference between a...Ch. 18 - Prob. 18.33ECh. 18 - Prob. 18.34ECh. 18 - List two structural differences between...Ch. 18 - Prob. 18.36ECh. 18 - Describe the structural similarities and...Ch. 18 - Give another name for glycolipids. In what tissues...Ch. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - How does the polarity of the phosphoglycerides...Ch. 18 - Prob. 18.42ECh. 18 - Prob. 18.43ECh. 18 - Prob. 18.44ECh. 18 - Explain how bile salts aid in the digestion of...Ch. 18 - Prob. 18.46ECh. 18 - Prob. 18.47ECh. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Prob. 18.50ECh. 18 - How are testosterone and progesterone structurally...Ch. 18 - Prob. 18.52ECh. 18 - Prob. 18.53ECh. 18 - Prob. 18.54ECh. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60ECh. 18 - Prob. 18.61ECh. 18 - Prob. 18.62ECh. 18 - Prob. 18.63ECh. 18 - Prob. 18.64ECh. 18 - Prob. 18.65ECh. 18 - Prob. 18.66ECh. 18 - Prob. 18.67ECh. 18 - Prob. 18.68ECh. 18 - Prob. 18.69ECh. 18 - Prob. 18.70ECh. 18 - Prob. 18.71ECh. 18 - When a doughnut is placed on a napkin, the napkin...Ch. 18 - Fats belong to the class of organic compounds...Ch. 18 - Identify each of the following characteristics as...Ch. 18 - Identify which sex hormones testosterone,...Ch. 18 - Prob. 18.76ECh. 18 - In diseases of the gallbladder, which of the...Ch. 18 - Steroids are classified as: a.carbohydrates....Ch. 18 - Accumulation of cholesterol leads to the hardening...Ch. 18 - Cholesterol, in spite of its bad reputation, is an...Ch. 18 - Bile is manufactured in the: a. duodenum. b....Ch. 18 - The basic structure of cell membrane is a: a....Ch. 18 - The mineralocorticoid _____ is a product of the...Ch. 18 - Prob. 18.84ECh. 18 - Prob. 18.85E
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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