Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 18, Problem 18.39E
Interpretation Introduction
Interpretation:
The location of the membranes that are found in a prokaryotic cell, and the eukaryotic cell is to be stated. The functions of the membranes are to be stated.
Concept introduction:
Lipids are organic compounds, which are fatty acids or the derivatives of fatty acids. They are insoluble in water but are soluble in non-polar organic solvents. Membranes are made up of lipids, which protect the organelles from the surroundings. The lipid membranes are selective in nature due to the bilayer arrangement of the lipids.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 18 Solutions
Chemistry for Today: General, Organic, and Biochemistry
Ch. 18 - What is the basis for deciding if a substance is a...Ch. 18 - List two major functions of lipids in the human...Ch. 18 - What functional group is common to all...Ch. 18 - Prob. 18.4ECh. 18 - Prob. 18.5ECh. 18 - Describe four structural characteristics exhibited...Ch. 18 - Describe the structure of a micelle formed by the...Ch. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Explain why the melting points of unsaturated...
Ch. 18 - What structural feature of a fatty acid is...Ch. 18 - How are fats and oils structurally similar? How...Ch. 18 - From Figure 18.7, arrange the following substances...Ch. 18 - Draw the structure of a triglyceride that contains...Ch. 18 - Prob. 18.15ECh. 18 - The percentage of fatty acid composition of two...Ch. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Why is the hydrogenation of vegetable oils of...Ch. 18 - Prob. 18.21ECh. 18 - Write reactions to show how each of the following...Ch. 18 - Draw the structure of a wax formed from oleic acid...Ch. 18 - Prob. 18.24ECh. 18 - Draw the structure of a wax formed from stearic...Ch. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Draw the general block diagram structure of a...Ch. 18 - Draw the structure of a phosphoglyceride...Ch. 18 - Describe two biological roles served by the...Ch. 18 - Prob. 18.31ECh. 18 - What is the structural difference between a...Ch. 18 - Prob. 18.33ECh. 18 - Prob. 18.34ECh. 18 - List two structural differences between...Ch. 18 - Prob. 18.36ECh. 18 - Describe the structural similarities and...Ch. 18 - Give another name for glycolipids. In what tissues...Ch. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - How does the polarity of the phosphoglycerides...Ch. 18 - Prob. 18.42ECh. 18 - Prob. 18.43ECh. 18 - Prob. 18.44ECh. 18 - Explain how bile salts aid in the digestion of...Ch. 18 - Prob. 18.46ECh. 18 - Prob. 18.47ECh. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Prob. 18.50ECh. 18 - How are testosterone and progesterone structurally...Ch. 18 - Prob. 18.52ECh. 18 - Prob. 18.53ECh. 18 - Prob. 18.54ECh. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60ECh. 18 - Prob. 18.61ECh. 18 - Prob. 18.62ECh. 18 - Prob. 18.63ECh. 18 - Prob. 18.64ECh. 18 - Prob. 18.65ECh. 18 - Prob. 18.66ECh. 18 - Prob. 18.67ECh. 18 - Prob. 18.68ECh. 18 - Prob. 18.69ECh. 18 - Prob. 18.70ECh. 18 - Prob. 18.71ECh. 18 - When a doughnut is placed on a napkin, the napkin...Ch. 18 - Fats belong to the class of organic compounds...Ch. 18 - Identify each of the following characteristics as...Ch. 18 - Identify which sex hormones testosterone,...Ch. 18 - Prob. 18.76ECh. 18 - In diseases of the gallbladder, which of the...Ch. 18 - Steroids are classified as: a.carbohydrates....Ch. 18 - Accumulation of cholesterol leads to the hardening...Ch. 18 - Cholesterol, in spite of its bad reputation, is an...Ch. 18 - Bile is manufactured in the: a. duodenum. b....Ch. 18 - The basic structure of cell membrane is a: a....Ch. 18 - The mineralocorticoid _____ is a product of the...Ch. 18 - Prob. 18.84ECh. 18 - Prob. 18.85E
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