Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 17.5, Problem 17.26KCP

(a)

Interpretation Introduction

Interpretation:

The structure of the repeating units of polymer which is made from the given compounds has to be given.

Concept introduction:

In chemistry structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Carboxylic acid: One OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Ester: One OR' group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOR'. The hydrogen atom of COOH is replaced by an alkyl group.

Esterification reaction: Esters are prepared by the reaction of a carboxylic acid and an alcohol molecule with the elimination of water molecule. The addition of a strong acid such as H2SO4 is used to increase the rate of reaction.

Here, the OH group is attached to the carbonyl carbon atom of the carboxylic acid is being replaced by OR' the in the alcohol forming ester and water.

Polyester: One COOH group of a dicarboxylic acid reacts with the one of the hydroxyl groups of a dialcohol results in the formation of an ester between them. Repeated linking of more molecule results in the formation of a polymer with ester linkage called polyester.

(b)

Interpretation Introduction

Interpretation:

The structure of the repeating units of polymer which is made from the given compounds has to be given.

Concept introduction:

In chemistry structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Carboxylic acid: One OH group is attached to the carbonyl carbon atom of the compound. It is represented as RCOOH

Amide: One NH2, NHR' or NR'2 group is attached to the carbonyl carbon atom of the compound. It is represented as RCONR'2.

Amide Formation: Amide is formed when a carboxylic acid reacts with an amine or ammonia.

Here, the OH group is attached to the carbonyl carbon atom of the carboxylic acid is being replaced by NH2, NHR' or NR'2 group in the an amine or ammonia forming amide and water.

Polyamide: One COOH group of a dicarboxylic acid reacts with the one of the amino groups of a diamine results in the formation of an amide between them. Repeated linking of more molecule results in the formation of a polymer with amide linkage called polyamide.

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Chapter 17 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 17.1 - Prob. 17.11PCh. 17.1 - Prob. 17.12PCh. 17.1 - Prob. 17.13KCPCh. 17.2 - Salsalate, which is an ester formed by the...Ch. 17.2 - Prob. 17.2CIAPCh. 17.2 - Prob. 17.3CIAPCh. 17.2 - Prob. 17.14PCh. 17.2 - Prob. 17.15PCh. 17.2 - Prob. 17.16PCh. 17.3 - Prob. 17.17PCh. 17.3 - Raspberry oil contains an ester that is made by...Ch. 17.3 - Prob. 17.19PCh. 17.3 - Prob. 17.20PCh. 17.3 - Prob. 17.21PCh. 17.4 - If a bottle of aspirin tablets has the aroma of...Ch. 17.4 - Prob. 17.23PCh. 17.4 - What carboxylic acids and amines result from...Ch. 17.5 - Prob. 17.25PCh. 17.5 - Prob. 17.26KCPCh. 17.6 - Prob. 17.27PCh. 17.6 - Prob. 17.28PCh. 17.6 - Prob. 17.4CIAPCh. 17.6 - Prob. 17.5CIAPCh. 17.6 - Prob. 17.29PCh. 17 - Prob. 17.30UKCCh. 17 - Prob. 17.31UKCCh. 17 - One phosphorylated form of glycerate is...Ch. 17 - Prob. 17.33UKCCh. 17 - Prob. 17.34UKCCh. 17 - Prob. 17.35UKCCh. 17 - Prob. 17.36UKCCh. 17 - For the following compounds, give the systematic...Ch. 17 - Write the equation for the ionization of hexanoic...Ch. 17 - Prob. 17.39APCh. 17 - Prob. 17.40APCh. 17 - Prob. 17.41APCh. 17 - Give systematic names for the following carboxylic...Ch. 17 - Give systematic names for the following carboxylic...Ch. 17 - Prob. 17.44APCh. 17 - Prob. 17.45APCh. 17 - Draw structures corresponding to the following...Ch. 17 - Draw structures corresponding to the following...Ch. 17 - Malic acid, a dicarboxylic acid found in apples,...Ch. 17 - Prob. 17.49APCh. 17 - Prob. 17.50APCh. 17 - Prob. 17.51APCh. 17 - Prob. 17.52APCh. 17 - Prob. 17.53APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.56APCh. 17 - Prob. 17.57APCh. 17 - Give systematic names for the following structures...Ch. 17 - Give systematic names for the following structures...Ch. 17 - Prob. 17.60APCh. 17 - What compounds are produced from hydrolysis of...Ch. 17 - Procaine, a local anesthetic whose hydrochloride...Ch. 17 - Prob. 17.63APCh. 17 - Lactones are cyclic esters in which the carboxylic...Ch. 17 - When both the carboxylic acid and the amine are in...Ch. 17 - LSD (lysergic acid diethylamide), a semisynthetic...Ch. 17 - Prob. 17.67APCh. 17 - Prob. 17.68APCh. 17 - Prob. 17.69APCh. 17 - Prob. 17.70APCh. 17 - Prob. 17.71APCh. 17 - Prob. 17.72APCh. 17 - Prob. 17.73APCh. 17 - Prob. 17.74APCh. 17 - Prob. 17.75APCh. 17 - Three amide isomers, N,N-dimethylformamide,...Ch. 17 - Prob. 17.77CPCh. 17 - Prob. 17.78CPCh. 17 - Mention at least two simple chemical tests by...Ch. 17 - Prob. 17.80CPCh. 17 - Name the following compounds.Ch. 17 - Each of the following materials has an ester that...Ch. 17 - Prob. 17.83GPCh. 17 - Prob. 17.84GP
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