Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 16, Problem 67E
Interpretation Introduction
Interpretation: The charge of the manganese ions in the compound manganese fluoride needs to be determined.
Concept Introduction: The formula of the compound is formed in such a way that the magnitude of charge of an atom is equal to the number of atoms of other atom present in the formula. For example, if the formula of the compound is
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Chapter 16 Solutions
Chemical Principles
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- A portion of the crystalline lattice for potassium is illustrated below. (a) In what type of unit cell are the K atoms arranged? A portion of the solid-state structure of potassium. (b) If one edge of the potassium unit cell is 533 pm, what is the density of potassium?arrow_forwardThe CsCl structure is a simple cubic array of chloride ions with a cesium ion at the center of each cubic array (see Exercise 69). Given that the density of cesium chloride is 3.97 g/cm3, and assuming that the chloride and cesium ions touch along the body diagonal of the cubic unit cell, calculate the distance between the centers of adjacent Cs+ and Cl ions in the solid. Compare this value with the expected distance based on the sizes of the ions. The ionic radius of Cs+ is 169 pm, and the ionic radius of Cl is 181 pm.arrow_forwardAn amorphous solid can sometimes be converted to a crystalline solid by a process called annealing. Annealing consists of heating the substance to a temperature just below the melting point of the crystalline form and then cooling it slowly. Explain why this process helps produce a crystalline solid.arrow_forward
- Why do the boiling points of the noble gases increase in the order HeNeArKrXe?arrow_forwardDescribe, in general, the structures of ionic solids. Compare and contrast the structure of sodium chloride and zinc sulfide. How many tetrahedral holes and octahedral holes are there per closest packed anion? In zinc sulfide, why are only one-half of the tetrahedral holes filled with cations?arrow_forwardA compound of thallium and iodine crystallizes in a simple cubic array of iodide ions with thallium ions in all of the cubic holes. What is the formula of this iodide? Explain your answer.arrow_forward
- Rubidium chloride has the sodium chloride structure at normal pressures but assumes the cesium chloride structure at high pressures. (See Exercise 69.) What ratio of densities is expected for these two forms? Does this change in structure make sense on the basis of simple models? The ionic radius is 148 pm for Rb+ and 181 pm for CI.arrow_forwardCalculate the percent of volume that is actually occupied by spheres in a body-centered cubic lattice of identical spheres You can do this by first relating the radius of a sphere, r, to the length of an edge of a unit cell, l. (Note that the spheres do not touch along an edge but do touch along a diagonal passing through the body-centered sphere.) Then calculate the volume of a unit cell in terms of r. The volume occupied by spheres equals the number of spheres per unit cell times the volume of a sphere (4r3/3).arrow_forwardExplain why liquids assume the shape of any container into which they are poured, whereas solids are rigid and retain their shape.arrow_forward
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