Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 16, Problem 39E
Interpretation Introduction
Interpretation: Whether
Concept Introduction: In ionic solids, the ions (formed by complete transfer of electrons from atoms) are present at the lattice points whereas in network solids, the boding between atoms is strong directional covalent bonding formed by sharing of electrons between the atoms. Due to presence of ions in ionic solids, they conduct electricity in aqueous solutions whereas there are no such ions present in network solids so, they do not conduct electricity in aqueous solutions.
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Synthesis of Dibenzalacetone
[References]
Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below.
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You do not have to consider stereochemistry.
. Draw the enolate ion in its carbanion form.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
⚫ Separate multiple reactants using the + sign from the drop-down menu.
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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
Chapter 16 Solutions
Chemical Principles
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