Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 16, Problem 34E
Interpretation Introduction
Interpretation: The term closest packing and the different between the hexagonal closest packing and cubic closest packing needs to be explained. The unit cell for each of the closest packing arrangement needs to be determined.
Concept Introduction: A unit cell is defined as the smallest repeating portion in the crystal lattice.
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Consider the following nucleophilic substitution reaction. The compound listed above the arrow is the solvent for the reaction. If nothing is listed over the arrow,
then the nucleophile is also the solvent for the reaction.
Part 1 of 2
Br
CH,CN
+ I¯
What is the correct mechanism for the reaction? Select the single best answer.
@SN2
○ SN 1
Part: 1/2
Part 2 of 2
Draw the products for the reaction. Include both the major organic product and the inorganic product. If more than one stereoisomer is possible, draw
only one stereoisomer. Include stereochemistry where relevant.
Click and drag to start drawing a
structure.
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20.33 Think-Pair-Share
(a) Rank the following dienes and dienophiles in order of increasing reactivity in the
Diels-Alder reaction.
(i)
CO₂Et
(ii)
COEt
||
CO₂Et
MeO
MeO
(b) Draw the product that results from the most reactive diene and most reactive
dienophile shown in part (a).
(c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc-
curs between the diene and dienophile in part (b).
(d) Is the major product formed in part (b) the endo or exo configuration? Explain
your reasoning.
Chapter 16 Solutions
Chemical Principles
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Ch. 16 - Prob. 11ECh. 16 - List the major types of intermolecular forces in...Ch. 16 - Prob. 13ECh. 16 - Prob. 14ECh. 16 - Prob. 15ECh. 16 - Prob. 16ECh. 16 - Prob. 17ECh. 16 - Prob. 18ECh. 16 - Rationalize the difference in boiling points for...Ch. 16 - Prob. 20ECh. 16 - Prob. 21ECh. 16 - Prob. 22ECh. 16 - Consider the following electrostatic potential...Ch. 16 - Prob. 24ECh. 16 - Prob. 25ECh. 16 - Prob. 26ECh. 16 - Prob. 27ECh. 16 - Prob. 28ECh. 16 - Prob. 29ECh. 16 - Prob. 30ECh. 16 - Prob. 31ECh. 16 - Prob. 32ECh. 16 - Prob. 33ECh. 16 - Prob. 34ECh. 16 - Prob. 35ECh. 16 - Prob. 36ECh. 16 - Prob. 37ECh. 16 - Prob. 38ECh. 16 - Prob. 39ECh. 16 - Prob. 40ECh. 16 - Prob. 41ECh. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - Prob. 44ECh. 16 - Prob. 45ECh. 16 - Prob. 46ECh. 16 - Nickel has a face-centered cubic unit cell. The...Ch. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Prob. 50ECh. 16 - Prob. 51ECh. 16 - The radius of tungsten is 137 pm and the density...Ch. 16 - Prob. 53ECh. 16 - Prob. 54ECh. 16 - Prob. 55ECh. 16 - Prob. 56ECh. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Prob. 61ECh. 16 - Prob. 62ECh. 16 - Describe, in general, the structures of ionic...Ch. 16 - Prob. 64ECh. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Prob. 67ECh. 16 - Prob. 68ECh. 16 - Prob. 69ECh. 16 - Prob. 70ECh. 16 - Prob. 71ECh. 16 - Prob. 72ECh. 16 - Prob. 73ECh. 16 - Prob. 74ECh. 16 - Prob. 75ECh. 16 - Prob. 76ECh. 16 - Prob. 77ECh. 16 - Perovskite is a mineral containing calcium,...Ch. 16 - Prob. 79ECh. 16 - Prob. 80ECh. 16 - Prob. 81ECh. 16 - Prob. 82ECh. 16 - How does each of the following affect the rate of...Ch. 16 - Prob. 84ECh. 16 - Prob. 85ECh. 16 - Prob. 86ECh. 16 - Prob. 87ECh. 16 - Diethyl ether (CH3CH2OCH2CH3) was one of the...Ch. 16 - Prob. 89ECh. 16 - Prob. 90ECh. 16 - A substance has the following properties: Sketch a...Ch. 16 - Prob. 92ECh. 16 - Prob. 93ECh. 16 - Prob. 94ECh. 16 - Prob. 95ECh. 16 - Prob. 96ECh. 16 - Prob. 97ECh. 16 - Prob. 98ECh. 16 - Compare and contrast the phase diagrams of water...Ch. 16 - Prob. 100ECh. 16 - Prob. 101ECh. 16 - Prob. 102ECh. 16 - Prob. 103ECh. 16 - Prob. 104ECh. 16 - Prob. 105ECh. 16 - Prob. 106ECh. 16 - The melting point of a fictional substance X is...Ch. 16 - Prob. 108ECh. 16 - Prob. 109ECh. 16 - Prob. 110AECh. 16 - Prob. 111AECh. 16 - Prob. 112AECh. 16 - Prob. 113AECh. 16 - Prob. 114AECh. 16 - Prob. 115AECh. 16 - Prob. 116AECh. 16 - Prob. 117AECh. 16 - Prob. 118AECh. 16 - Prob. 119AECh. 16 - Prob. 120AECh. 16 - Prob. 121AECh. 16 - Spinel is a mineral that contains 37.9%...Ch. 16 - Prob. 123AECh. 16 - Prob. 124AECh. 16 - Prob. 125AECh. 16 - Prob. 126AECh. 16 - Prob. 127AECh. 16 - Prob. 128AECh. 16 - Prob. 129AECh. 16 - Prob. 130AECh. 16 - Prob. 131AECh. 16 - Prob. 132AECh. 16 - Prob. 133AECh. 16 - Prob. 134AECh. 16 - Prob. 135AECh. 16 - Prob. 136AECh. 16 - Which of the following statements is(are) true? a....Ch. 16 - Prob. 138AECh. 16 - Prob. 139AECh. 16 - Prob. 140AECh. 16 - Prob. 141AECh. 16 - Prob. 142AECh. 16 - Prob. 143AECh. 16 - Prob. 144CPCh. 16 - Prob. 145CPCh. 16 - Prob. 146CPCh. 16 - Prob. 147CPCh. 16 - Prob. 148CPCh. 16 - Prob. 149CPCh. 16 - Prob. 150CPCh. 16 - Prob. 151CPCh. 16 - Prob. 152CPCh. 16 - Prob. 153CPCh. 16 - Prob. 154MP
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- 20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a tricyclic product. Propose a structural formula for the product. CN heat An intramolecular Diels-Alder adductarrow_forwardno Ai walkthroughsarrow_forwardWhat is the reaction mechanism for this? Can this even be done without a base?arrow_forward
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. + Drawing Arrows CH3ONA, CH3OH heat : Br:O Na → H H Br Na + H H H H H :0: .H + Undo Reset Done Q CH3 Drag To Pan +arrow_forwardWhat is the reaction mechanism for this?arrow_forward20.19 Predict the structure of the major 1,2-addition product formed by reaction of one mole of Cl₂ with 3-methylenecyclohexene. Also predict the structure of the 1,4-addition product formed under these conditions. 20.20 Which of the two molecules shown do you expect to be the major product formed by 1,2-addition of HCI to cyclopentadiene? Explain. Cyclopentadiene + HC 3-Chlorocyclopentene (racemic) or 4-Chlorocyclopentene (racemic)arrow_forward
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