Concept explainers
(a)
Interpretation:
For the given ketone IUPAC name has to be assigned.
Concept Introduction:
For naming a ketone in
IUPAC rules for naming a ketone:
- • The longest parent carbon chain is identified that includes the carbonyl group.
- • The parent chain name is changed by replacing the suffix “-e” with “-one”.
- • Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.
- • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
- • Cyclic
ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.
In a line-angle structural formula, carbon atom is present in the point where the lines intersect and the end point.
(b)
Interpretation:
For the given ketone IUPAC name has to be assigned.
Concept Introduction:
For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.
IUPAC rules for naming a ketone:
- • The longest parent carbon chain is identified that includes the carbonyl group.
- • The parent chain name is changed by replacing the suffix “-e” with “-one”.
- • Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.
- • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
- • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.
In a line-angle structural formula, carbon atom is present in the point where the lines intersect and the end point.
(c)
Interpretation:
For the given ketone IUPAC name has to be assigned.
Concept Introduction:
For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.
IUPAC rules for naming a ketone:
- • The longest parent carbon chain is identified that includes the carbonyl group.
- • The parent chain name is changed by replacing the suffix “-e” with “-one”.
- • Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.
- • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
- • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.
In a line-angle structural formula, carbon atom is present in the point where the lines intersect and the end point.
(d)
Interpretation:
For the given ketone IUPAC name has to be assigned.
Concept Introduction:
For naming a ketone in IUPAC nomenclature, the suffix “-one” is added to the parent alkane name.
IUPAC rules for naming a ketone:
- • The longest parent carbon chain is identified that includes the carbonyl group.
- • The parent chain name is changed by replacing the suffix “-e” with “-one”.
- • Numbering is done in a way that the carbonyl group gets the least numbering. The position of the carbonyl group is indicated in the name.
- • The identity and location of substituents if any has to be determined and this information has to be added in front of the IUPAC name.
- • Cyclic ketones are named by adding the suffix “-one” to the name of the carbon ring. The substituents are numbered so that it gets the least numbering starting from the carbonyl group that is given the number 1.
In a line-angle structural formula, carbon atom is present in the point where the lines intersect and the end point.
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Chapter 15 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- From your calculations, which reaction experiment had closest to stoichiometric quantities? How many moles of NaHCO3 and HC2H3O2 were present in this reaction?arrow_forward18. Arrange the following carbocations in order of decreasing stability. 1 2 A 3124 B 4213 C 2431 D 1234 E 2134 SPL 3 4arrow_forwardAcetic acid is added to DI water at an initial concentration of 10 -6 M (Ka=1.8x10-5) A. Using the "ICE" Method, what would the pH be at equilibrium? State assumptions and show your work. B. Using the simultaneous equations method, what would the pH be at equilibrium? Show your workarrow_forward
- 1. Show that the change in entropy for a fixed amount of ideal gas held at a constant temperature undergoing a volume change is given by the simple equation AS = NkB In Hint: Start with the equation M dS = du + (Œ) dv - Ž (#) an, dU du+av-dN; j=1 Why doesn't the equation for the entropy of an ideal gas depend on the strength of the intermolecular forces for the gas?arrow_forward2. Make an ice cube at 1 bar pressure by freezing an amount of liquid water that is 2 cm x 2 cm x 2 cm in volume. The density of liquid water at 0 °C is 1.000 g cm³ and the density of ice at 0 °C is 0.915 g cm³. Note that this difference in density is the reason your water pipes burst if they freeze and why you shouldn't forget to take your bottle of pop out of the freezer if you put it in there to try and cool it down faster. A. What is the work of expansion upon freezing? B. Is work done on the system or by the system?arrow_forwardI have a excitation/emission spectra of a quinine standard solution here, and I'm having trouble interpreting it. the red line is emission the blue line is excitation. i'm having trouble interpreting properly. just want to know if there is any evidence of raman or rayleigh peaks in the spectra.arrow_forward
- Give the major product of the following reaction. excess 1. OH, H₂O 1.OH H CH3CH2CH21 H 2. A.-H₂O Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.arrow_forward2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forwardci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)arrow_forward
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