Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 14, Problem 68E
A student dissolves 0.0100 mole of an unknown weak base in 100.0 mL water and titrates the solution with 0.100 M HNO3. After 40.0 mL of 0.100 M HNO3 was added, the pH of the resulting solution was 8.00. Calculate the Kb value for the weak base.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a) The following synthesis of the molecule shown in the circle has a major problem. What is this problem? (2
pts)
1) HBr
(no peroxides)
2) H-
NaNH2
Br
3) NaNH,
4) CH3Br
5) H2, Pd
(b) Starting with the molecule shown below and any other materials with two carbons or less, write out an
alternate synthesis of the circled molecule. More than one step is needed. Indicate the reagent(s) and the major
product in all the steps in your synthesis. (5 pts)
2024 Fall Term (1) Organic Chemistry 1 (Lec)
CHEM 22204 02[6386] (Hunter College)
(c) Using the same starting material as in part (b) and any other materials win two carpons or less, write out
syntheses of the circled molecules shown below. More than one step is needed in each case. Indicate the
reagent(s) and the major product in all the steps in your synthesis. You may use reactions and products from
your synthesis in part (b). (5 pts)
alt
ons for
Free Response Questions
FRQ 1:
0/5
To spectrophotometrically determine the mass percent of cobalt in an ore containing cobalt and
some inert materials, solutions with known [Co?) are prepared and absorbance of each of the
solutions is measured at the wavelength of optimum absorbance. The data are used to create a
calibration plot, shown below.
0.90-
0.80-
0.70
0.60
0.50
0.40-
0.30
0.20-
0.10-
0.00-
0.005
0.010
Concentration (M)
0.015
A 0.630 g sample of the ore is completely dissolved in concentrated HNO3(aq). The mixture is diluted
with water to a final volume of 50.00 ml. Assume that all the cobalt in the ore sample is converted to
Co2+(aq).
a. What is the [Co2] in the solution if the absorbance of a sample of the solution is 0.74?
13
✗
b. Calculate the number of moles of Co2+(aq) in the 50.00 mL solution.
0.008 mols Co
Please correct answer and don't used hand raiting
Chapter 14 Solutions
Chemistry: An Atoms First Approach
Ch. 14 - What is meant by the presence of a common ion? How...Ch. 14 - Define a buffer solution. What makes up a buffer...Ch. 14 - Prob. 3RQCh. 14 - A good buffer generally contains relatively equal...Ch. 14 - Prob. 5RQCh. 14 - Prob. 6RQCh. 14 - Sketch the titration curve for a weak acid...Ch. 14 - Sketch the titration curve for a weak base...Ch. 14 - What is an acidbase indicator? Define the...Ch. 14 - Prob. 10RQ
Ch. 14 - What are the major species in solution after...Ch. 14 - Prob. 2ALQCh. 14 - Prob. 3ALQCh. 14 - Prob. 4ALQCh. 14 - Sketch two pH curves, one for the titration of a...Ch. 14 - Prob. 6ALQCh. 14 - Prob. 7ALQCh. 14 - You have a solution of the weak acid HA and add...Ch. 14 - The common ion effect for weak acids is to...Ch. 14 - Prob. 10QCh. 14 - Prob. 11QCh. 14 - Consider the following pH curves for 100.0 mL of...Ch. 14 - An acid is titrated with NaOH. The following...Ch. 14 - Consider the following four titrations. i. 100.0...Ch. 14 - Prob. 15QCh. 14 - Prob. 16QCh. 14 - How many of the following are buffered solutions?...Ch. 14 - Which of the following can be classified as buffer...Ch. 14 - A certain buffer is made by dissolving NaHCO3 and...Ch. 14 - Prob. 20ECh. 14 - Calculate the pH of each of the following...Ch. 14 - Calculate the pH of each of the following...Ch. 14 - Prob. 23ECh. 14 - Compare the percent ionization of the base in...Ch. 14 - Prob. 25ECh. 14 - Calculate the pH after 0.020 mole of HCl is added...Ch. 14 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 14 - Calculate the pH after 0.020 mole of NaOH is added...Ch. 14 - Which of the solutions in Exercise 21 shows the...Ch. 14 - Prob. 30ECh. 14 - Calculate the pH of a solution that is 1.00 M HNO2...Ch. 14 - Calculate the pH of a solution that is 0.60 M HF...Ch. 14 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 14 - Calculate the pH after 0.10 mole of NaOH is added...Ch. 14 - Calculate the pH of each of the following buffered...Ch. 14 - Prob. 36ECh. 14 - Calculate the pH of a buffered solution prepared...Ch. 14 - A buffered solution is made by adding 50.0 g NH4Cl...Ch. 14 - Prob. 39ECh. 14 - An aqueous solution contains dissolved C6H5NH3Cl...Ch. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Consider a solution that contains both C5H5N and...Ch. 14 - Calculate the ratio [NH3]/[NH4+] in...Ch. 14 - Prob. 45ECh. 14 - Prob. 46ECh. 14 - Prob. 47ECh. 14 - Prob. 48ECh. 14 - Calculate the pH of a solution that is 0.40 M...Ch. 14 - Calculate the pH of a solution that is 0.20 M HOCl...Ch. 14 - Which of the following mixtures would result in...Ch. 14 - Prob. 52ECh. 14 - Prob. 53ECh. 14 - Calculate the number of moles of HCl(g) that must...Ch. 14 - Consider the titration of a generic weak acid HA...Ch. 14 - Sketch the titration curve for the titration of a...Ch. 14 - Consider the titration of 40.0 mL of 0.200 M HClO4...Ch. 14 - Consider the titration of 80.0 mL of 0.100 M...Ch. 14 - Consider the titration of 100.0 mL of 0.200 M...Ch. 14 - Prob. 60ECh. 14 - Lactic acid is a common by-product of cellular...Ch. 14 - Repeat the procedure in Exercise 61, but for the...Ch. 14 - Repeat the procedure in Exercise 61, but for the...Ch. 14 - Repeat the procedure in Exercise 61, but for the...Ch. 14 - Prob. 65ECh. 14 - In the titration of 50.0 mL of 1.0 M methylamine,...Ch. 14 - You have 75.0 mL of 0.10 M HA. After adding 30.0...Ch. 14 - A student dissolves 0.0100 mole of an unknown weak...Ch. 14 - Prob. 69ECh. 14 - Prob. 70ECh. 14 - Potassium hydrogen phthalate, known as KHP (molar...Ch. 14 - A certain indicator HIn has a pKa of 3.00 and a...Ch. 14 - Prob. 73ECh. 14 - Prob. 74ECh. 14 - Prob. 75ECh. 14 - Prob. 76ECh. 14 - Prob. 77ECh. 14 - Estimate the pH of a solution in which crystal...Ch. 14 - Prob. 79ECh. 14 - Prob. 80ECh. 14 - Prob. 81AECh. 14 - Prob. 82AECh. 14 - Tris(hydroxymethyl)aminomethane, commonly called...Ch. 14 - Prob. 84AECh. 14 - You have the following reagents on hand: Solids...Ch. 14 - Prob. 86AECh. 14 - Prob. 87AECh. 14 - What quantity (moles) of HCl(g) must be added to...Ch. 14 - Calculate the value of the equilibrium constant...Ch. 14 - The following plot shows the pH curves for the...Ch. 14 - Calculate the volume of 1.50 102 M NaOH that must...Ch. 14 - Prob. 92AECh. 14 - A certain acetic acid solution has pH = 2.68....Ch. 14 - A 0.210-g sample of an acid (molar mass = 192...Ch. 14 - The active ingredient in aspirin is...Ch. 14 - One method for determining the purity of aspirin...Ch. 14 - A student intends to titrate a solution of a weak...Ch. 14 - Prob. 98AECh. 14 - Prob. 99AECh. 14 - Consider 1.0 L of a solution that is 0.85 M HOC6H5...Ch. 14 - Prob. 101CWPCh. 14 - Consider the following acids and bases: HCO2H Ka =...Ch. 14 - Prob. 103CWPCh. 14 - Prob. 104CWPCh. 14 - Consider the titration of 100.0 mL of 0.100 M HCN...Ch. 14 - Consider the titration of 100.0 mL of 0.200 M...Ch. 14 - Prob. 107CWPCh. 14 - Prob. 108CPCh. 14 - A buffer is made using 45.0 mL of 0.750 M HC3H5O2...Ch. 14 - A 0.400-M solution of ammonia was titrated with...Ch. 14 - Prob. 111CPCh. 14 - Consider a solution formed by mixing 50.0 mL of...Ch. 14 - When a diprotic acid, H2A, is titrated with NaOH,...Ch. 14 - Consider the following two acids: In two separate...Ch. 14 - The titration of Na2CO3 with HCl bas the following...Ch. 14 - Prob. 116CPCh. 14 - A few drops of each of the indicators shown in the...Ch. 14 - Malonic acid (HO2CCH2CO2H) is a diprotic acid. In...Ch. 14 - A buffer solution is prepared by mixing 75.0 mL of...Ch. 14 - A 10.00-g sample of the ionic compound NaA, where...Ch. 14 - Prob. 121IPCh. 14 - Prob. 122MP
Additional Science Textbook Solutions
Find more solutions based on key concepts
How could you separate a mixture of the following compounds? The reagents available to you are water, either, 1...
Organic Chemistry (8th Edition)
6. How can you use the features found in each chapter?
Human Anatomy & Physiology (2nd Edition)
56. Global Positioning System. Learn more about the global positioning system and its uses. Write a short repo...
The Cosmic Perspective (8th Edition)
Some people consider Pasteur or Koch to be the Father of Microbiology, rather than Leeuwenhoek. Why might they ...
Microbiology with Diseases by Body System (5th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Closo-boranes and arachno-boranes are structures that exhibit B-B, B-H-B, and B-H bonds. Correct?arrow_forwardIndicate why boron hydrides cannot form large linear or planar structures.arrow_forwardNido-boranes are structures with the molecular formula BnHn+4 that exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forward
- 8:07 AM Wed Dec 18 Final Exam 2024 copy Home Insert Draw Page Layout Formulas Data Review AA 田 General A G fx Alexis Cozort ☑ ⚫ 61% A B D E F H K M N P R S T U 3+ 10 125 mM that yielded peak heights of Aa = 9 1-(a)A sample solution was examined under XRF to quantify the analyte Ce³+. Find the response factor F, when standardized concentration of analyte [Ce³+]A = concentration of internal standard S i.e. [In³*]s = 151 mM was spiked with standardized 1600 and As = 3015 respectively? 11 12 (i)Define F, F = Aa As [A] [S] + X 13 (*Define with variables) 4000 14 15 (ii)Calculate F, F = numeral (You will use the F value in part 1-(b) below) As 16 (*Calculate with numerals) 17 18 1-(b)To determine the unknown conc of analyte [Ce³+], a volume of 15 mL of internal standard S having a concentration [In³+]s = 0.264 M 19 20 was added to 45 mL of unknown, and the mixture was diluted to 100 mL in a volumetric flask. XRF analysis yielded a spectrum, Figure-1, where peak heights A and As are…arrow_forwardAll structural types of Boron hydrides exhibit B-B, B-H-B and B-H bonds. Correct?arrow_forwardN-nitrosodimethylamine (NDMA) is a suspected carcinogen that can form via reactions between dimethylamine (DMA) and monochloramine (NH2Cl). The relevant elementary reactions and the corresponding rate constants are as shown below. Reaction Rate constant (M¹s¹) DMA + NH2Cl = DMCA + NH3 k =1.4×10-1, kr = 5.83×10-3 1.28×10-3 DMA + NH2Cl → UDMH UDMH + NH2Cl → NDMA -> 1.11×10-1 If the initial concentrations of DMA and NH2Cl are given, you should be able to predict the concentrations of all species at any given reaction time. Please write down the rate equations for DMA, NH2C1, DMCA, UDMH and NDMA.arrow_forward
- You wish to add enough NaOCl (sodium hypochlorite) to a 150 m³ swimming pool to provide a dose of 5.0 mg/L TOTOCI as Cl2. (a) How much NaOCI (kg) should you add? (Note: the equivalent weight of NaOCl is based on the reaction: NaOCl + 2H + 2 e→CI + Na +H₂O.) (10 pts) (atomic weight: Na 23, O 16, C1 35.5) (b) The pH in the pool after the NaOCl addition is 8.67. To improve disinfection, you want at least 90% of the TOTOCI to be in the form of HOCI (pKa 7.53). Assuming that HOCI/OCI is the only weak acid/base group in solution, what volume (L) of 10 N HCl must be added to achieve the goal? (15 pts) Note that part a) is a bonus question for undergraduate students. If you decide not to work on this part of the question, you many assume TOTOCI = 7×10-5 M for part b).arrow_forwardPart A 2K(s)+Cl2(g)+2KCI(s) Express your answer in grams to three significant figures. Part B 2K(s)+Br2(1)→2KBr(s) Express your answer in grams to three significant figures. Part C 4Cr(s)+302(g)+2Cr2O3(s) Express your answer in grams to three significant figures. Part D 2Sr(s)+O2(g) 2SrO(s) Express your answer in grams to three significant figures. Thank you!arrow_forwardA solution contains 10-28 M TOTCO3 and is at pH 8.1. How much HCI (moles per liter of solution) is required to titrate the solution to pH 7.0? (H2CO3: pKa1=6.35, pKa2=10.33)arrow_forward
- Don't used Ai solutionarrow_forwardThe standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?arrow_forwardClassification of boranes.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY