The standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter16: Spontaneity Of Reaction
Section: Chapter Questions
Problem 62QAP: Consider the reaction NH4+(aq) H+(aq)+NH3(aq) Use G f for NH3(aq) at 25C=26.7 kJ/mol and the...
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The standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are
-604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the
following reaction:
CaCO3 CaO (s) + CO2 (g)
[ap
A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in
contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is
the total Gibbs free energy of the system containing all three species before any reaction has
happened? Does the equilibrium driving force favor conversion of one of the solids into the
other, or are the solids equilibrated with one another?
Transcribed Image Text:The standard Gibbs energies of formation of CaO(s), CaCO3 (calcite), and CO2 (g) are -604.04, -1128.80, and -394.37 kJ/mol, respectively. Find the value of AG, and Keq for the following reaction: CaCO3 CaO (s) + CO2 (g) [ap A dry mixture containing 1 g of each solid [CaCO3(s) and CaO(s)] is on the lab bench in contact with the atmosphere, which contains a partial pressure of 10-35 bar CO2 (g). What is the total Gibbs free energy of the system containing all three species before any reaction has happened? Does the equilibrium driving force favor conversion of one of the solids into the other, or are the solids equilibrated with one another?
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