Concept explainers
Interpretation: The information about solving the acid–base problem and problems involving reaction of strong acid and strong base is given. The substance that reacts with
Concept introduction: The solution whose
To determine: The substance that reacts with
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Chemistry: An Atoms First Approach
- Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forwardConsider the following ions: NH4+, CO32, Br, S2, and ClO4. (a) Which of these ions in water gives an acidic solution and which gives a basic solution? (b) Which of these anions will have no effect on the pH of an aqueous solution? (c) Which ion is the strong base? (d) Write a chemical equation for the reaction of each basic anion with water.arrow_forwardStrong Acids, Weak Acids, and pH Two 0.10-mol samples of the hypothetical monoprotic acids HA(aq) and HB(aq) are used to prepare 1.0-L stock solutions of each acid. a Write the chemical reactions for these acids in water. What are the concentrations of the two acid solutions? b One of these acids is a strong acid, and one is weak. What could you measure that would tell you which acid was strong and which was weak? c Say that the HA(aq) solution has a pH of 3.7. Is this the stronger of the two acids? How did you arrive at your answer? d What is the concentration of A(aq) in the HA solution described in part c? e If HB(aq) is a strong acid, what is the hydronium-ion concentration? f In the solution of HB(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), B(aq), HB(aq), or OH(aq)? How did you decide? g In the solution of HA(aq), which of the following would you expect to be in the greatest concentration: H3O+(aq), A+(aq), HA(aq), or OH(aq)? How did you decide? h Say you add 1.0 L of pure water to a solution of HB. Would this water addition make the solution more acidic, make it less acidic, or not change the acidity of the original solution? Be sure to fully justify your answer. i You prepare a 1.0-L solution of HA. You then take a 200-mL sample of this solution and place it into a separate container. Would this 200 mL sample be more acidic, be less acidic, or have the same acidity as the original 1.0-L solution of HA(aq)? Be sure to support your answer.arrow_forward
- Most naturally occurring acids are weak acids. Lactic acid is one example. CH3CH(OH)CO2H(s)+H2O(l)H3O+(aq)+CH3CH(OH)CO2(aq) If you place some lactic acid in water, it will ionize to a small extent, and an equilibrium will be established. Suggest some experiments to prow that this is a weak acid and that the establishment of equilibrium is a reversible process.arrow_forwardExplain why the pH does not change significantly when a small amount of an acid or a base is added to a solution that contains equal amounts of the acid H3PO4 and a salt of its conjugate base NaH2PO4.arrow_forwardWhat is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?arrow_forward
- What is meant by the presence of a common ion? How does the presence of a common ion affect an equilibrium such as HNO2(aq) H+(aq) + NO2-(aq) What is an acidbase solution called that contains a common ion?arrow_forwardUse the same symbols as in Question 61 ( = anion, =OH) for the box below. (a) Fill in a similar box (representing one liter of the same solution) after 2 mol of H+ (2) have been added. Indicate whether the resulting solution is an acid, base, or buffer. (b) Follow the directions of part (a) for the resulting solution after 2 mol of OH- (2 ) have been added. (c) Follow the directions of part (a) for the resulting solution after 5 mol of OH- (5 ) have been added. (Hint: Write the equation for the reaction before you draw the results.)arrow_forwardAqueous Solutions of Acids, Bases, and Salts a For each of the following salts, write the reaction that occurs when it dissociates in water: NaCl(s), NaCN(s), KClO2(s), NH4NO3(s), KBr(aq), and NaF(s). b Consider each of the reactions that you wrote above, and identify the aqueous ions that could be proton donors (acids) or proton acceptors (bases). Briefly explain how you decided which ions to choose. c For each of the acids and bases that you identified in pan b, write the chemical reaction it can undergo in aqueous solution (its reaction with water). d Are there any reactions that you have written above that you anticipate will occur to such an extent that the pH of the solution will be affected? As pan of your answer, be sure to explain how you decided. e Assume that in each case above, 0.01 mol of the salt was dissolved in enough water at 25C to make 1.0 L of solution. In each case what additional information would you need in order to calculate the pH? If there are cases where no additional information is required, be sure to state that as well. f Say you take 0.01 mol of NH4CN and dissolve it in enough water at 25C to make 1.0 L of solution. Using chemical reactions and words, explain how you would go about determining what effect this salt will have on the pH of the solution. Be sure to list any additional information you would need to arrive at an answer.arrow_forward
- An aqueous solution contains formic acid and formate ion. Determine the direction in which the pH will change if each of the following chemicals is added to the solution. (a) HCl (b) NaHSO4 (c) CH3COONa (d) KBr (e) H2Oarrow_forwardUsing the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.arrow_forward(a) What is the pH of a 0.105 M HCl solution? (b) What is the hydronium ion concentration in a solution with a pH of 2.56? Is the solution acidic or basic? (c) A solution has a pH of 9.67. What is the hydronium ion concentration in the solution? Is the solution acidic or basic? (d) A 10.0-mL sample of 2.56 M HCl is diluted with water to 250. mL What is the pH of the dilute solution?arrow_forward
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