Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 14, Problem 57E
Interpretation Introduction
Interpretation: The bonding in
Concept Introduction:
Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.
Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals.
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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless
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2) H3O+
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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:
QUESTION: Summarise and report these results including an indication of measurement uncertainty.
In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).
Mass of Taurine (mg)
Mass of Taurine (mg)
(Table continued)
152.01
152.23
151.87
151.45
154.11
152.64
152.98
153.24
152.88
151.45
153.49
152.48
150.68
152.33
151.52
153.63
152.48
151.68
153.17
153.40
153.77
153.67
152.34
153.16
152.57
153.02
152.86
151.50
151.23
152.57
152.72
151.54
146.47
152.38
152.44
152.54
152.53
152.54
151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
Chapter 14 Solutions
Chemical Principles
Ch. 14 - Prob. 1DQCh. 14 - Prob. 2DQCh. 14 - Prob. 3DQCh. 14 - Prob. 4DQCh. 14 - Prob. 5DQCh. 14 - Prob. 6DQCh. 14 - Compare and contrast the MO model with the LE...Ch. 14 - Prob. 8DQCh. 14 - Prob. 9ECh. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Use the localized electron model to describe the...Ch. 14 - Prob. 15ECh. 14 - Use the LE model to describe the bonding in H2CO...Ch. 14 - Prob. 17ECh. 14 - The space-filling models of hydrogen cyanide and...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Indigo is the dye used in coloring blue jeans. The...Ch. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Why must all six atoms in C2H4 be in the same...Ch. 14 - The allene molecule has the following Lewis...Ch. 14 - Biacetyl and acetoin are added to margarine to...Ch. 14 - Many important compounds in the chemical industry...Ch. 14 - Prob. 29ECh. 14 - Hot and spicy foods contain molecules that...Ch. 14 - Two molecules used in the polymer industry are...Ch. 14 - Prob. 32ECh. 14 - The three most stable oxides of carbon are carbon...Ch. 14 - Prob. 34ECh. 14 - Prob. 35ECh. 14 - What are the relationships among bond order, bond...Ch. 14 - Prob. 37ECh. 14 - A Lewis structure obeying the octet rule can be...Ch. 14 - Prob. 39ECh. 14 - Why does the molecular orbital model do a better...Ch. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - In which of the following diatomic molecules would...Ch. 14 - Prob. 45ECh. 14 - Using the molecular orbital model to describe the...Ch. 14 - The transport of O2 in the blood is carried out by...Ch. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Consider the following electron configuration:...Ch. 14 - Prob. 51ECh. 14 - Using an MO energy-level diagram, would you expect...Ch. 14 - Use Figs.14.45 and 14.46 to answer the following...Ch. 14 - The diatomic molecule OH exists in the gas phase....Ch. 14 - Prob. 55ECh. 14 - Describe the bonding in the O3 molecule and the...Ch. 14 - Prob. 57ECh. 14 - The space-filling model for benzoic acid is shown...Ch. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - The microwave spectrum of 12C16O shows that the...Ch. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - Draw the Lewis structures, predict the molecular...Ch. 14 - Prob. 66AECh. 14 - Prob. 67AECh. 14 - Prob. 68AECh. 14 - Prob. 69AECh. 14 - Prob. 70AECh. 14 - Prob. 71AECh. 14 - Prob. 72AECh. 14 - Prob. 73AECh. 14 - Vitamin B6 is an organic compound whose deficiency...Ch. 14 - Prob. 75AECh. 14 - Prob. 76AECh. 14 - Prob. 77AECh. 14 - Prob. 78AECh. 14 - Prob. 79AECh. 14 - Draw the Lewis structures for TeCl4 , ICl5 , PCl5...Ch. 14 - Prob. 81AECh. 14 - Pelargondin is the molecule responsible for the...Ch. 14 - Prob. 83AECh. 14 - Prob. 84AECh. 14 - Prob. 85AECh. 14 - Prob. 86AECh. 14 - Given that the ionization energy of F2 is...Ch. 14 - Bond energy has been defined in the text as the...Ch. 14 - a.A flask containing gaseous N2 is irradiated with...Ch. 14 - Use the MO model to determine which of the...Ch. 14 - Cholesterol (C27H46O) has the following structure:...Ch. 14 - Arrange the following from lowest to highest...Ch. 14 - Carbon monoxide (CO) forms bonds to a variety of...Ch. 14 - Prob. 94CPCh. 14 - In Exercise71 in Chapter13 , the Lewis structures...Ch. 14 - Prob. 96CPCh. 14 - Prob. 97CPCh. 14 - Prob. 98MP
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- PROBLEMS Q1) Label the following salts as either acidic, basic, or neutral a) Fe(NOx) c) AlBr b) NH.CH COO d) HCOON (1/2 mark each) e) Fes f) NaBr Q2) What is the pH of a 0.0750 M solution of sulphuric acid?arrow_forward8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مدarrow_forwardA J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3arrow_forward
- 1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.arrow_forward3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward
- 4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forwardArrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidityarrow_forward1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)arrow_forward
- Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forwardThe rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward
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