Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 14, Problem 77AE

(a)

Interpretation Introduction

Interpretation: The arrangement of N2O molecule as NNO or NON needs to be determined, if N2O molecule is considered as a linear and polar.

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

Formal charge on each atom can be determined with the help of number of valence shell electrons, number of lone pair electrons and bond pair electrons. The formula for the formal charge can be written as:

  FC = VE – LE – bond pairFC= formal chargeVE = Valence electrons LE= number of lone pair electrons Bond pair = Number of bond pairs

(b)

Interpretation Introduction

Interpretation: The Lewis structure of N2O molecule including resonance structure with the hybridization and formal charge needs to be determined.

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

Formal charge on each atom can be determined with the help of number of valence shell electrons, number of lone pair electrons and bond pair electrons. The formula for the formal charge can be written as:

  FC = VE – LE – bond pairFC= formal chargeVE = Valence electrons LE= number of lone pair electrons Bond pair = Number of bond pairs

(c)

Interpretation Introduction

Interpretation: The orbitals involves in the given structure of N2O molecule needs to be determined.

  Chemical Principles, Chapter 14, Problem 77AE

Concept Introduction:

Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that existing on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.

Formal charge on each atom can be determined with the help of number of valence shell electrons, number of lone pair electrons and bond pair electrons. The formula for the formal charge can be written as:

  FC = VE – LE – bond pairFC= formal chargeVE = Valence electrons LE= number of lone pair electrons Bond pair = Number of bond pairs

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(a) Use the VSEPR theory to predict the structure of theNNO molecule.(b) The substance NNO has a small dipole moment.Which end of the molecule is more likely to be thepositive end, based only on electronegativity?
1. Draw the Lewis structures for each of the following ions or molecules. For each, give (i) the molecular shape, (ii) the electron pair geometry at the central atom, and (iii) the hybridization of the central atom. (a) POF3 (b) XeO₂F3+ (c) BrCl₂ (d) N3 (the central atom is N; two other N's are bonded to it) (e) PF3
Consider the reaction BF3 + NH3 -> F3B-NH3 (a) Describe the changes in hybridization of the B and N atoms as a result of this reaction. (b) Describe the shapes of all the reactant molecules with their bond angles. (c) Draw the overall shape of the product molecule and identify the bond angles around B and N atoms. (d) What is the name of the bond between B and N. (e)Describe the bonding orbitals that make the B and F, B and N & N and H bonds in the product molecule.

Chapter 14 Solutions

Chemical Principles

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