General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 13, Problem 47P
Interpretation Introduction
Interpretation:
Double bonds of the following cycloalkane should be labeled as cis or trans.
Concept Introduction:
Cis-trans isomers are fall under geometric isomerism.
Cis isomers- two different groups are on the same side of the double bond.
Trans isomers- two different groups are on opposite sides of the double bond.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Based on naming branched alkyl substituents, and draw all possible alkyl groups having the formula C5H11–. Give the IUPAC names for the eight compounds of molecular formula C10H20that contain a cyclopentane ring with each of these alkyl groups as a substituent.
Why is a 1, 3 - cis disubstituted cyclohexane more stable than its trans isomer?
The heat of combustion of cyclononane is 5586 kJ/mol (1335 kcal/mol). Calculate the ring strain per CH2 group and the total ring strain of cyclononane. Which compound has more ring strain, cyclononane or cycloheptane?
Chapter 13 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.1PCh. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.2PPCh. 13.2 - Prob. 13.3PCh. 13.2 - Prob. 13.3PPCh. 13.2 - Prob. 13.4PPCh. 13.3 - Prob. 13.5PPCh. 13.3 - Prob. 13.4PCh. 13.3 - Prob. 13.6PP
Ch. 13.3 - Prob. 13.5PCh. 13.3 - Prob. 13.6PCh. 13.3 - Prob. 13.7PCh. 13.3 - Prob. 13.8PCh. 13.6 - Prob. 13.7PPCh. 13.6 - Prob. 13.9PCh. 13.6 - What products is formed in each of the following...Ch. 13.6 - Prob. 13.9PPCh. 13.6 - What product is formed when l-pentene (CH3CH2CH2CH...Ch. 13.7 - Prob. 13.11PCh. 13.8 - Prob. 13.10PPCh. 13.8 - Prob. 13.12PCh. 13.8 - Prob. 13.13PCh. 13.10 - Prob. 13.11PPCh. 13.10 - Prob. 13.14PCh. 13.11 - Prob. 13.15PCh. 13.12 - Prob. 13.16PCh. 13.13 - Prob. 13.17PCh. 13.13 - Prob. 13.18PCh. 13 - Anethole, the major constituent of anise oil, is...Ch. 13 - Prob. 20PCh. 13 - What is the molecular formula for a hydrocarbon...Ch. 13 - Prob. 22PCh. 13 - Prob. 23PCh. 13 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each molecule depicted in...Ch. 13 - Give the IUPAC name for each compound. a....Ch. 13 - Give the IUPAC name for each compound. d....Ch. 13 - Give the IUPAC name for each alkene.Ch. 13 - Give the I UP AC name for each alkene.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the IUPAC name for each cyclic compound.Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 36PCh. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Each of the following IUPAC names is incorrect....Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Label the carbon-carbon double bond as cis or...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Prob. 48PCh. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Prob. 51PCh. 13 - Prob. 52PCh. 13 - Prob. 53PCh. 13 - Prob. 54PCh. 13 - What alkyd halide is formed when each alkene is...Ch. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - What alkene is needed as a starting material to...Ch. 13 - Prob. 60PCh. 13 - Prob. 61PCh. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - Prob. 64PCh. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - Prob. 68PCh. 13 - Prob. 69PCh. 13 - Prob. 70PCh. 13 - Prob. 71PCh. 13 - Prob. 72PCh. 13 - Prob. 73PCh. 13 - Are o-bromochlorobenzene and m-bromochlorobenzene...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Give the structure corresponding to each IUPAC...Ch. 13 - Prob. 77PCh. 13 - Prob. 78PCh. 13 - Prob. 79PCh. 13 - Prob. 80PCh. 13 - Prob. 81PCh. 13 - Prob. 82PCh. 13 - Prob. 83PCh. 13 - Prob. 84PCh. 13 - Prob. 85PCh. 13 - Eleostearic acid is an unsaturated fatty acid...Ch. 13 - Prob. 87PCh. 13 - Prob. 88PCh. 13 - Prob. 89PCh. 13 - Prob. 90PCh. 13 - Prob. 91PCh. 13 - Prob. 92PCh. 13 - Prob. 93PCh. 13 - Prob. 94PCh. 13 - Answer the following questions about compound A,...Ch. 13 - Prob. 96PCh. 13 - Answer the following questions about alkene C,...Ch. 13 - Prob. 98PCh. 13 - Prob. 99PCh. 13 - Prob. 100PCh. 13 - Prob. 101CPCh. 13 - Prob. 102CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Place the methyl groups by drawing the axial and equatorial positions on the cyclohexane structure in the chair conformations next to the cyclohexane derivatives named below.arrow_forwardWhen cyclohexane is substituted by an ethynyl group, -C=CH, the energy difference between axial and equatorial conformations is only 1.7 kJ (0.41 kcal)/mol. Compare the conformational equilibrium for methylcyclohexane with that for ethynylcyclohexane and account for the difference between the two.arrow_forwardDraw the structure(s) of the cycloalkanes with molecular formula C6H12 that have a 3-membered ring and two substituents.arrow_forward
- Determine which cyclohexane structure has the MOST energy (is the LEAST stable)?arrow_forwardDraw all the possible conformations of trans- and cis-1,3-dimethylcyclobutane. Which of these conformations is the most stable conformation? Explain your answer. Discuss the type of strain(s) that affect the stability of these compounds.arrow_forward4. Which structure below represents the most stable conformation of cis-1-t-butyl-4-methylcyclohexane? A B D 5. The planar form of which ring would have bond angles close to the tetrahedral value, but is destabilized by eclipsing interactions (torsional strain)? Which of the following statements about conformations is FALSE? A) Conformations can be isolated and separated at room temperature B) Conformations are interconverted by rotation about o-bonds C) For butane the staggered anti conformation is the most stable D) For ethane the eclipsed conformation is the least stable 6. 7. Which of the following compounds has two chirality centers? .H H. H3Carrow_forward
- How many alkenes have the molecular formula C5H10, ie structural isomers with a double bond. Count cis and trans isomers as separate compounds? 3 S 8arrow_forwardThe heats of hydrogenation of cycloheptene and 1,3,5-cycloheptatriene are 110 kJ/mol (26.3 kcal/mol) and 305 kJ/mol (73.0 kcal/mol), respectively. In both cases cycloheptane is the product. What is the resonance energy of 1,3,5-cycloheptatriene? How does it compare with the resonance energy of benzene?arrow_forwardWhen cyclopropane is treated with HI, 1-idopropane is formed. A similar type of reaction does not occur with cyclopentene or Cyclohexane. Suggest an explanation for cyclopropane’s reactivity.arrow_forward
- Name the following molecule. CH₂CH3 H-CH3 H3C H Br (2R, 3R)-2-bromo-3-methylpentane (2S,3S)-2-bromo-3-methylpentane O (2R,3S)-2-bromo-3-methylpentane (1R, 2S)-1-bromo-1,2-dimethylbutane (1S,2R)-1-bromo-1,2-dimethylbutanearrow_forwardCompounds X and Y are stereoisomers having the formula C6H12.Both X and Y react with one molar equivalent of hydrogen in the presence of a palladium catalyst to form hexane, and they each react with HBr to give a single bromoalkane product.Draw structural formulas for both X and Y.arrow_forwardDraw the two chair conformations for each of the following compounds and indicate which conformer is more stable.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Organic And Biological Chemistry
Chemistry
ISBN:9781305081079
Author:STOKER, H. Stephen (howard Stephen)
Publisher:Cengage Learning,
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning