Structural formula of the product for the alkene addition reaction has to be given. Concept Introduction: Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction. In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below, Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

Question

(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?

Answer 1

Question

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?

b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction with Mg in ether. CI Br ד c) Circle the Grignard reagents that contain incompatible functional groups. MgBr HO MgBr MgBr MgBr MgBr HO MgBr

Q2: Predict all organic product(s), including stereoisomers when applicable. PCC OH a) CH2Cl2 Page 2 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) .OH Na2Cr2O7, H+ OH PCC CH2Cl2 c) OH

Answer 2

Question

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 3

Question

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 4

Question

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

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Answer 5

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 6

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

Answer 7

Chapter 13, Problem 13.78EP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Halogenation is an example of addition reaction. In this reaction, a halogen molecule is incorporated into the molecules of organic compound. Halogenation of alkene results in the formation of dihaloalkane, where both carbon atoms bonded by double bond gets halogen atom.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrohalogenation is an example of addition reaction. In this reaction, a hydrogen halide molecule is incorporated into the molecules of organic compound. Hydrohalogenation of alkene results in the formation of haloalkane, where one carbon atom gets hydrogen atom added and the other carbon atom gets halogen group added to it.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydrogenation is an example of addition reaction. In this reaction, a hydrogen molecule is incorporated into the molecules of organic compound. Hydrogenation of alkene results in the formation of alcohol, where both carbon atoms bonded by double bond gets hydrogen atom. This reaction requires a metal as catalyst.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structural formula of the product for the alkene addition reaction has to be given.

Concept Introduction:

Chemical reaction in which an atom or a group of atoms are added to each carbon atom of a carbon‑carbon multiple bond in a hydrocarbon or hydrocarbon derivative is known as addition reaction.

In this reaction no atoms or group of atoms are removed. Instead the unsaturated bond is reduced to saturated bond. A general scheme for addition reaction of alkene can be given as shown below,

Hydration is an example of addition reaction. In this reaction, a water molecule is incorporated into the molecules of organic compound. Hydration of alkene results in the formation of alcohol, where one carbon atom gets hydrogen atom added and the other carbon atom gets hydroxyl group added to it. This reaction requires a small amount of sulphuric acid as catalyst.

Answer 14

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Ch. 13.1 - Prob. 1QQ Ch. 13.1 - Prob. 2QQ Ch. 13.1 - Prob. 3QQ Ch. 13.2 - Prob. 1QQ Ch. 13.2 - Prob. 2QQ Ch. 13.2 - Prob. 3QQ Ch. 13.2 - Prob. 4QQ Ch. 13.3 - Prob. 1QQ Ch. 13.3 - Prob. 2QQ Ch. 13.3 - Prob. 3QQ

Solution Summary: The author explains the structure of the product for the alkene addition reaction.

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