
Concept explainers
Interpretation:
Among the given options, the correct pairing of prefix and the numbering system used for locating substituents has to be chosen.
Concept Introduction:
Benzene derivatives are compounds that contain benzene as the core with substituents in the benzene ring. This is done by replacement of one or more hydrogen atoms with other atoms in the ring. Substituents like alkyl groups or halogen groups are generally found. IUPAC name for monosubstituted benzene derivative use the name of the substituents as prefix to the name benzene.
If two substituents are present in the benzene ring, then it is known as disubstituted benzene derivative. Three isomers are possible for disubstituted benzene. The three isomers can be given as,
If the substitution is in first and second position, then it is known as ortho substitution. If the substitution is in first and third position, then it is known as meta substitution. If the substitution is in first and fourth position, then it is known as para substitution.

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Chapter 13 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
- no Ai walkthroughsarrow_forward136 PRACTICAL SPECTROSCOPY Compound 78 is a high-boiling liquid (boiling point 189° C) that contains halogen, but will not react with alkoxides to yield an halogen. ether. The Mass, IR, and 'H NMR spectra, along with 13C NMR data, are given below. Elemental Analysis: C, 35.32; H, 2.47; contains BC Spectral Data: doublet, 137.4 ppm; doublet, 130.1 ppm; doublet, 127.4 ppm; singlet, 97.3 ppm Absorbance Mass Spectrum Intensity 77 77 204 M + 128 40 60 80 100 120 140 160 180 m/e 200 220 280 240 260 300 Infrared Spectrum Wave Number, cm -1 4000 3000 2500 2000 1500 1300 1200 1100 1000 900 800 700 3 6 7 8 9 10 12 13 15 Wavelength, microns 'H NMR wwwww 5 Structure: www ppm, & ©2000 Brooks/Cole Publishing Com-arrow_forwardno Ai walkthroughsarrow_forward
- 3. Synthesize the following synthon from the indicated starting material. i HO.arrow_forwardIdentifying the stereochemistry of natural Write the complete common (not IUPAC) name of each molecule below. Note: if a molecule is one of a pair of enantiomers, be sure you start its name with D- or L- so we know which enantiomer it is. molecule H O-C-CH2 H3N. HN N H C=O common name (not the IUPAC name) NH3 ☐ H3N H ☐ CH2 Xarrow_forward> Draw the structure of alanine at pH 1.2. Click and drag to start drawing a structure.arrow_forward
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning

