Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 12.4, Problem 6P
Draw the structure for each of the following:
- a. 3-hexanone
- b. β-methylbutyraldehyde
- c. isopropyl propyl
ketone
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Write a balanced equation for the hydrogenation of eachof the following:a. Hexanal (a six-carbon aldehyde)b. 2-Hexanone (a six-carbon ketone)c. 2-Methylbutanal (an aldehyde with a four-carbon parent chain)d. 6-Ethyl-2-octanone (a ketone with an eight-carbon parent chain)
Write a balanced equation for the hydrogenation of eachof the following:a. Propanal (a three-carbon aldehyde)b. Propanone (a three-carbon ketone)c. 2,3-Dimethylheptanal (an aldehyde with a seven-carbon parent chain)d. 3-Methyl-4-heptanone (a ketone with a seven-carbonparent chain)
10. Draw a structural formula for each of the fol 'owing esters:
a. cyclohexyl propanoate
b. methyl formate
c. ethyl benzoate
d. isopropyl acetate
e. butyl butanoate
f. propyl pentanoate
Chapter 12 Solutions
Essential Organic Chemistry, Global Edition
Ch. 12.1 - Prob. 1PCh. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3PCh. 12.1 - Prob. 4PCh. 12.2 - Prob. 5PCh. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7PCh. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9PCh. 12.5 - Prob. 10P
Ch. 12.5 - Prob. 12PCh. 12.5 - Write the mechanism for the reaction of acetyl...Ch. 12.5 - Prob. 14PCh. 12.6 - Prob. 16PCh. 12.7 - Prob. 17PCh. 12.7 - Prob. 18PCh. 12.7 - Prob. 19PCh. 12.8 - Prob. 20PCh. 12.8 - Prob. 21PCh. 12.8 - Prob. 22PCh. 12.9 - Which of the following are a. hemiacetals? b....Ch. 12.9 - Prob. 24PCh. 12.9 - Prob. 25PCh. 12.10 - Prob. 26PCh. 12.11 - Prob. 27PCh. 12 - Draw the structure for each of the following: a....Ch. 12 - Prob. 29PCh. 12 - List the following compounds in order from most...Ch. 12 - Show the reagents required to form the primary...Ch. 12 - Fill in the boxes:Ch. 12 - Indicate how the following compounds could be...Ch. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Prob. 39PCh. 12 - Show two ways the following compound could be...Ch. 12 - Prob. 41PCh. 12 - Prob. 42PCh. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Prob. 46PCh. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Prob. 50PCh. 12 - Prob. 51PCh. 12 - Indicate how the following compounds could be...Ch. 12 - Prob. 53P
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- Write a balanced equation for the hydrogenation of eachof the following aldehydes:a. 3-Methylbutanal c. Propanalb. 4-Bromopentanalarrow_forwardDraw the structure of each of the following compounds:a. Propanoneb. 2-Pentanonec. 3-Heptanoned. 2,4-Dimethyl-3-pentanonearrow_forwardDraw each of the following alcohols: a. 1-Iodo-2-butanol b. 1,2-Butanediol c. Cyclobutanolarrow_forward
- 7. Write a balanced equation for the hydrogenation of each of the following aldehydes: a. 3-Methylpentanal b. 2-Hydroxypropanal c. 2,3-Dimethylpentanal d. 4-Chloropentanal e. 2-Methyl-3-pentanone f. 3-Hexanonearrow_forwardGrignard reagents react with aldehyde to form: а. Carbon dioxide b. Secondary alcohol С. Ketone d. Carboxylic acidarrow_forward69. The structure of the aldehyde or ketone that the following compound came from: H A. III only B. IV only C. I and IV D. II only IVarrow_forward
- An aldehyde can be oxidized to produce a carboxylic acid.Draw the carboxylic acid that would be produced by theoxidation of each of the following aldehydes:a. 3-Methylpentanal c. 2,4-Diethylhexanalb. 2,3-Dichlorobutanal d. 2-Methylpropanalarrow_forward10. Under certain conditions interacts with sodium nitrite: A. Resorcinol B. Nicotinic acid C. Butadion D. Morphine hydrochloride E. Benzoic acidarrow_forward1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forward
- When phenol is treated with excess of bromine water, which of the following product it gives? Select one: a. 2-Bromophenol b. 2,4-Dibromophenol c. 2,4,6-Tribromophenol d. 2,3,4-Tribromophenolarrow_forwardThe type of intermediate formed when HgSO4/H2SO4/H2O is added to an alkyne is: a.an alcohol b.an aldehyde c.an enol d.a diol e.a ketonearrow_forward12. Write a balanced equation for each of the following reactions: a. Hydration of 1-butyne b. Hydration of 2-butynearrow_forward
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