Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 12.7, Problem 19P

(a)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Benzylmethylamine on reaction with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Ethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  2

(c)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Diethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  3

(d)

Interpretation Introduction

Interpretation:

It should be determined that the amide used to produce Triethylamine on rection with LiAlH4.

Concept introduction:

LiAH4 (Lithium aluminium hydride):

Lithium aluminium hydride is used as a reducing agent.

Lithium aluminium hydride is reduced the amide as an amine which is shown below.

Essential Organic Chemistry, Global Edition, Chapter 12.7, Problem 19P , additional homework tip  4

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What amides would you react with LiAlH4 to form the following amines? a. benzylmethylamine          c. diethylamine b. ethylamine                       d. triethylamine
What amides would you react with LiAlH4 to form the following amines?a. benzylmethylamine c. diethylamineb. ethylamine d. triethylamine
Draw condensed and skeletal structures for each of the following amines a. 2-methyl-N-propyl-1-propanamine b. N-ethylethanamine c. 5-methyl-1-hexanamine d. methyldipropylaminee. e. N,N-dimethyl-3-pentanamine  f. cyclohexylethylmethylamine
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