To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant. Concept introduction: The Grignard reaction: Alkyl, vinyl, or aryl-magnesium halides ( RMgX ) is called as Grignard reagent. Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone , produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

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Answer 1

Question

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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These reagents can produce ketones with alkynes A. BH3, THF, H2O2 B. KMnO4 C. O3 D. H2SO4, H2O, HgSO4

PLEASE HELP Draw the products formed when cyclohexene is treated with each reagent.

Draw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr g. TsCl, pyridine b. NaH h. [1] NaH; [2] CH₂CH₂Br e. SOCI₂, pyridine f. PBr3 c. HCI + ZnCl₂ Hint: NaH deprotonates the alcohol forming an alkoxide

Answer 2

Question

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 3

Question

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 4

Question

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

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Answer 5

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 6

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

Answer 7

Chapter 12, Problem 45P

(a)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Grignard reagent is reaction with carbonyl compound such as aldehyde or ketone, produces corresponding alcohol is the product and it is the one of the carbon – carbon bond forming reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 11

(c)

Interpretation Introduction

Interpretation:

To identify the products are formed when 3-methyl-2-cyclohexenone reacts with each of the given reactant.

Concept introduction:

Michael reaction:

The nucleophile is reaction with α,β-unsaturated carbonyl compound (1,4 –addtion) which yield the addition product is called Michael reaction.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains how 3-methyl-2-cyclohexenone reacts with alkyl, vinyl, or aryl-magnesium halides.

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