World of Chemistry
7th Edition
ISBN: 9780618562763
Author: Steven S. Zumdahl
Publisher: Houghton Mifflin College Div
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Chapter 12.4, Problem 3RQ
Interpretation Introduction
Interpretation:
The reason why molecular structure of some molecules is different from the structure given by arrangement of electron pairs is to be written.
Concept introduction:
To determine the shape of molecule, the total number of bonding and non-bonding pairs is to be calculated for the central atom. Then these are arranged in a shape so that electron- electron repulsions are minimum.
Expert Solution & Answer
Answer to Problem 3RQ
The molecular structure for a molecule is different from the arrangement of electron pairs when central atom has non- bonding pairs of electrons.
Explanation of Solution
According to VSEPR theory, lone pair-lone pair repulsions are maximum. If in a molecule central atom has lone pair of electrons then its structure will be little different from the structure suggested by arrangement of electron pairs.
Example:
Ammonia has pyramidal shape although it has 4 pairs of electrons around nitrogen.
Conclusion
Thus, if there is presence of non-bonding electrons, the structure will be different from the structure as given by arrangement of electron pairs.
Chapter 12 Solutions
World of Chemistry
Ch. 12.1 - Prob. 1RQCh. 12.1 - Prob. 2RQCh. 12.1 - Prob. 3RQCh. 12.1 - Prob. 4RQCh. 12.1 - Prob. 5RQCh. 12.1 - Prob. 6RQCh. 12.2 - Prob. 1RQCh. 12.2 - Prob. 2RQCh. 12.2 - Prob. 3RQCh. 12.2 - Prob. 4RQ
Ch. 12.2 - Prob. 5RQCh. 12.2 - Prob. 6RQCh. 12.2 - Prob. 7RQCh. 12.3 - Prob. 1RQCh. 12.3 - Prob. 2RQCh. 12.3 - Prob. 3RQCh. 12.3 - Prob. 4RQCh. 12.4 - Prob. 1RQCh. 12.4 - Prob. 2RQCh. 12.4 - Prob. 3RQCh. 12.4 - Prob. 4RQCh. 12.4 - Prob. 5RQCh. 12 - Prob. 1ACh. 12 - Prob. 2ACh. 12 - Prob. 3ACh. 12 - Prob. 4ACh. 12 - Prob. 5ACh. 12 - Prob. 6ACh. 12 - Prob. 7ACh. 12 - Prob. 8ACh. 12 - Prob. 9ACh. 12 - Prob. 10ACh. 12 - Prob. 11ACh. 12 - Prob. 12ACh. 12 - Prob. 13ACh. 12 - Prob. 14ACh. 12 - Prob. 15ACh. 12 - Prob. 16ACh. 12 - Prob. 17ACh. 12 - Prob. 18ACh. 12 - Prob. 19ACh. 12 - Prob. 20ACh. 12 - Prob. 21ACh. 12 - Prob. 22ACh. 12 - Prob. 23ACh. 12 - Prob. 24ACh. 12 - Prob. 25ACh. 12 - Prob. 26ACh. 12 - Prob. 27ACh. 12 - Prob. 28ACh. 12 - Prob. 29ACh. 12 - Prob. 30ACh. 12 - Prob. 31ACh. 12 - Prob. 32ACh. 12 - Prob. 33ACh. 12 - Prob. 34ACh. 12 - Prob. 35ACh. 12 - Prob. 36ACh. 12 - Prob. 37ACh. 12 - Prob. 38ACh. 12 - Prob. 39ACh. 12 - Prob. 40ACh. 12 - Prob. 41ACh. 12 - Prob. 42ACh. 12 - Prob. 43ACh. 12 - Prob. 44ACh. 12 - Prob. 45ACh. 12 - Prob. 46ACh. 12 - Prob. 47ACh. 12 - Prob. 48ACh. 12 - Prob. 49ACh. 12 - Prob. 50ACh. 12 - Prob. 51ACh. 12 - Prob. 52ACh. 12 - Prob. 53ACh. 12 - Prob. 54ACh. 12 - Prob. 55ACh. 12 - Prob. 56ACh. 12 - Prob. 57ACh. 12 - Prob. 58ACh. 12 - Prob. 59ACh. 12 - Prob. 60ACh. 12 - Prob. 61ACh. 12 - Prob. 62ACh. 12 - Prob. 63ACh. 12 - Prob. 1STPCh. 12 - Prob. 2STPCh. 12 - Prob. 3STPCh. 12 - Prob. 4STPCh. 12 - Prob. 5STPCh. 12 - Prob. 6STPCh. 12 - Prob. 7STPCh. 12 - Prob. 8STPCh. 12 - Prob. 9STP
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