EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12, Problem 48P
Interpretation Introduction
Interpretation:
The reason should be explained why the reaction does not following the given mechanism.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.
Propagation: In this stage, two steps are involving hydrogen abstraction and halogen abstraction (no change in the number of free radicals).
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
what are the 2 examples of mechanism reaction of alcohol oxidation and dehydration
25. Study the following reaction energy diagram:
Write a synthesis reaction for this mechanism:
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the initiation, propagation, and two example termination steps for this reaction. Include these steps under the headings "initiation": "propagation", and "termination". With reference to your mechanism, which one of the two possible products shown is formed? Also, show two checks that your propagation steps are correct. CN CN H₂C-C-N-N-C-CH₂ CH₂ CH₂ CH,SH A SCH, Of SCH₂arrow_forwardThe chlorination of propane proceeds as a radical chain reaction. hv 2 CH,CH,CH, + 2Cl, CH, CH,CH,Cl + CH,CHCICH, + 2 HCl Sort the 7 reaction steps (you may need to scroll down to see them all) into categories of initation, propagation and termination.arrow_forwardconsider the mechanism of the reaction shown below. Give the structure of the next important organic reaction intermediate alond the reaction coordinate. Your answer could be the final productarrow_forward
- How Calcium Oxide (CaO) is a heterogeneous based catalyst? How important it is in transesterification? *cite some sources :Darrow_forwardThe conversion of (CH3)3CI to (CH3)2C=CH2 can occur by either a onestepor a two-step mechanism, as shown in Equations [1] and [2]. Question: Assume Equation [2] represents an endothermic reaction and that the product of the rate-determining step is higher in energy than thereactants or products. Draw an energy diagram for this two-stepreaction. Label the axes, reactants and products for each step, and theEa and ΔHo for each step. Label ΔHo overall. Draw the structure for bothtransition states.arrow_forwardWrite a step-by-step mechanism using half arrows and draw reaction- energy profile diagram (two curves for minor and major products) for the first and second propagation steps when propane (CH3CH2CH3) reacts with chlorine (Cl₂) under light initiated condition. Label the parts that represent the reactants, intermediates, transition states, and activation energy. Write about a sentence what is Hammond postulate for this reaction.arrow_forward
- Q2. Carbonic Anhydrase or carbonic dehydratase is a family of metalloenzymes containing zinc (Zn) ion in its active site. Carbonic anhydrase can greatly increase the rate of this reaction, reaching a reaction rate of 104 - 106 per second. It is defined as the enzyme found in red blood cells, other parts of animals and plants, that breaks down carbonic acid with carbon dioxide and water. CO:(2) – H»O(1) – H.CO:(ag) For the carbonic anhydrase activity specified by the equation above, evaluate the standard reaction Gibbs energy at 25 °C?arrow_forwardConsider a chemical reaction between compound A and compound B. The reaction proceeds via a multi-step mechanism involving several intermediates and transition states. The overall reaction is exothermic, but one of the intermediate steps is endothermic. Explain how the endothermic intermediate step can still be consistent with the overall exothermic nature of the reaction.arrow_forward33arrow_forward
- Pretend that the exponent that [Sn²+ ] is raised to in the rate law expression is 1.0236. Pretend that the exponent that [H,O*] is raised to in the rate law expression is 0.9526. Finally, pretend that for one of your runs that the kexpt = 0.0047, [H,O+] = 0.8474, and [Sn²+] = 0.0066. Determine the rate constant, k, for that run. k=arrow_forwardConsider this reaction: CH2=CH2 + H2 → CH3-CH3 What would the Rate Law be for this reaction? Rate = k [H2]n CH2=CH2 + H2 → CH3-CH3 Rate = k [CH3-CH3]n [H2]m Rate = k [CH2=CH2 ]n Rate = k [CH2=CH2]n [H2]m Rate = k [CH2=CH2]n [CH3-CH3]marrow_forwardExplain why methyl alcohol reacts with HBr faster than other primary alcohols?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Enzymes - Effect of cofactors on enzyme; Author: Tutorials Point (India) Ltd;https://www.youtube.com/watch?v=AkAbIwxyUs4;License: Standard YouTube License, CC-BY
Enzyme Catalysis Part-I; Author: NPTEL-NOC IITM;https://www.youtube.com/watch?v=aZE740JWZuQ;License: Standard Youtube License