The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given. Concept introduction: Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical. Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength. Chlorination: 2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

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Answer 1

Question

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Answer 2

Question

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

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Answer 3

Question

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

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Answer 4

Question

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

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Answer 5

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

Answer 6

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Answer 7

Chapter 12, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The number of chlorination product obtained from radical chlorination of methylcyclohexane has to be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product obtained in greater yield should be given and explained.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

Answer 11

(c)

Interpretation Introduction

Interpretation:

The number of monochlorination products obtained by considering all stereoisomers should be given.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

Bond strength is depends on the formation of the radical, if the radical is involving in resonance which is weakest bond strength.

Chlorination:

2-methylpropane undergoes radical chlorination which yields the 2-chloro-2-methylpropane and 1-chloro-2-methylpropane.

Chiral: Four different atoms attached to a carbon atom is called chiral molecule.

Stereoisomers: Stereoisomers are molecules that have the same molecular formula and they differ only in arrangement of atom in three-dimensional space.

Enantiomers: A compound which is non-superimposable mirror image is called enantiomers.

Diastereomers: A compound which is non-superimposable and non-mirror image is called enantiomers

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer

Answer 12

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Answer 13

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Answer 15

Ch. 12.2 - Prob. 1P Ch. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3P Ch. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6P Ch. 12.5 - Prob. 8P Ch. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12P Ch. 12.7 - Prob. 13P

Solution Summary: The author explains that the number of chlorination products obtained from radical methylcyclohexane should be given and explained.

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