EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 12.4, Problem 4P
How many alkyl chlorides are obtained from monochlorination of the following
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Chlorination of alkanes can produce a multitude of products. Determine the number of monochlorinated and dichlorinated products that can be obtained by chlorination of 3‑methylpentane. (Consider constitutional isomers only. Do not count stereoisomers.)
In this task you should explain structural isomerism in aliphatic alkanes and geometric isomerism in alkenes.
Explain the role strain plays on stability and reactivity of a cyclic alkane such as cyclopropane.
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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- How many monochloro substitution products are produced when the alkanes below are chlorinated? Consider constitutional isomers only, ignore stereoisomers. a) b) The number of monochloro substitution products is 4 The number of monochloro substitution products is 3 X.arrow_forwardDraw all of the constitutional (structural) isomers that can be formed from the monochlorination of the hydrocarbon shown below. CH3 CH3 hv CH3 Cl2 + H3C- CH3 エーO-エarrow_forwardAlkyl halides can be converted into alkanes by which reaction?arrow_forward
- how to name cyclic or acyclic alkanes ? what are the steps and rules that I have to follow to name anyone that comes my wayarrow_forwardWhat alkane, with molecular formula C7H16, forms seven monochlorinated products (disregarding stereoisomers) when heated with Cl2?arrow_forwardThe most reactive among the other hydrocarbons. O Alkynes O Alkenes Alkanes Arenes These compounds are completely conjugated ring aromatic if they are planar and have 4n + 2 pi electrons. rger than benzene are also pyridine annulene рyrrole anthracene This type of hydrocarbons contain only single bonds and are sp3 hybridized. Unsaturated hydrocarbons O Saturated hydrocarbons O Polyunsaturated hydrocarbons Supersaturated hydrocarbonsarrow_forward
- a) What products would you expect from the elimination reaction of 3-Bromo-2- methylpentane? Show the reaction by writing the condensed structural formula of the reactants and products. Identify the major and minor products. b) What alkyl halide might the 3,6-Dimethyl-1- heptene have been made from?arrow_forwardHaloalkanes undergo nucleophilic substitution whereas haloarenes undergo electrophilic substitution. Explain.arrow_forwardAn alkylbromide [X] produces single alkene[Y] when it reacts with sodium ethoxide and ethanol. [Y] upon hydrogenation produces 2-methylbutane. Choose the correct statement(s) among the following [X] is a tertiary alky bromide [X] is a primary alky bromide [X] may or may not show stereoisomerism [Y] can exhibit geometrical isomerismarrow_forward
- Which among the following is a terminal alkene? propene cyclohexene cis-2-Butene 1-butynearrow_forwardPlease be clear in your writing The following names may have some errors. Correct the name and render the structures corresponding to the following names. g) 1,3-pentadiino h) cyclohexylacetylenearrow_forwardA cycloalkene forms methylcyclohexane when catalytically reduced and 1,2-dichloro-4-methylcyclohexane when treated with Cl,. Draw the structural formula of the cycloalkene.arrow_forward
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How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY