IUPAC name for the given alkane has to be written. Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word. Prefix represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. Root word represents the longest continuous carbon skeleton of the organic molecule. To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Question

The following table is from Kumar et. al. Highly Selective Dopamine D3 Receptor (DR) Antagonists and Partial Agonists Based on Eticlopride and the D3R Crystal Structure: New Leads for Opioid Dependence Treatment. J. Med Chem 2016.

Answer 1

Question

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 2

Question

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 3

Question

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Expert Solution & Answer

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Answer 4

Question

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

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Answer 5

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 6

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 7

Chapter 12, Problem 12.51EP

(a)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 8

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 9

(b)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 10

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 11

(c)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 12

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 13

(d)

Interpretation Introduction

Interpretation:

IUPAC name for the given alkane has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane, the first step is to find the longest carbon chain. The next step is to identify the substituents that are present in the longest carbon chain. The numbering has to be given in a way that the substituents get the least numbering.

Answer 14

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Answer 25

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains that any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).

Chapter 12 Solutions