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Chapter 12, Problem 12.103EP

(a)

Interpretation Introduction

Interpretation:

The wrong thing with the given name of cycloalkane has to be given using IUPAC rules.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

The IUPAC name for cycloalkane can be obtained simply by adding prefix cyclo- before the alkane name which corresponds to the total number of carbon atoms that are present in the ring.  To name a cycloalkane, the first step is to find the longest carbon chain that makes a cyclic ring without any unsaturation.  The next step is to identify the substituents that are present in the cyclic ring structure.  The numbering has to be given in a way that the substituents get the least numbering.

(b)

Interpretation Introduction

Interpretation:

The wrong thing with the given name of cycloalkane has to be given using IUPAC rules.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

The IUPAC name for cycloalkane can be obtained simply by adding prefix cyclo- before the alkane name which corresponds to the total number of carbon atoms that are present in the ring.  To name a cycloalkane, the first step is to find the longest carbon chain that makes a cyclic ring without any unsaturation.  The next step is to identify the substituents that are present in the cyclic ring structure.  The numbering has to be given in a way that the substituents get the least numbering.

(c)

Interpretation Introduction

Interpretation:

The wrong thing with the given name of cycloalkane has to be given using IUPAC rules.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

The IUPAC name for cycloalkane can be obtained simply by adding prefix cyclo- before the alkane name which corresponds to the total number of carbon atoms that are present in the ring.  To name a cycloalkane, the first step is to find the longest carbon chain that makes a cyclic ring without any unsaturation.  The next step is to identify the substituents that are present in the cyclic ring structure.  The numbering has to be given in a way that the substituents get the least numbering.

(d)

Interpretation Introduction

Interpretation:

The wrong thing with the given name of cycloalkane has to be given using IUPAC rules.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).  IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule.  It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

The IUPAC name for cycloalkane can be obtained simply by adding prefix cyclo- before the alkane name which corresponds to the total number of carbon atoms that are present in the ring.  To name a cycloalkane, the first step is to find the longest carbon chain that makes a cyclic ring without any unsaturation.  The next step is to identify the substituents that are present in the cyclic ring structure.  The numbering has to be given in a way that the substituents get the least numbering.

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Give the correct IUPAC name for the following cycloalkene. A. cis-3,4-dimethylcycloheptene B. cis-3,4-dimethylheptene O C. cis-6,7-dimethylcycloheptene D. cis-dimethylcycloheptene
1. Draw the structure of each of the following cycloalkanes a. 1-Bromo-2-methylcyclobutaneb. 1,2-Dibromo-3-methylcyclohexanec. Iodocyclopropane2. How does the general formula of a cycloalkane compare to that of an alkane?

Chapter 12 Solutions

Bundle: General, Organic, and Biological Chemistry, 7th + OWLv2 Quick Prep for General Chemistry, 4 terms (24 months) Printed Access Card

Ch. 12.5 - Prob. 2QQCh. 12.5 - Prob. 3QQCh. 12.6 - Prob. 1QQCh. 12.6 - Prob. 2QQCh. 12.6 - Prob. 3QQCh. 12.6 - Prob. 4QQCh. 12.7 - Prob. 1QQCh. 12.7 - Prob. 2QQCh. 12.8 - Prob. 1QQCh. 12.8 - Prob. 2QQCh. 12.8 - Prob. 3QQCh. 12.8 - Prob. 4QQCh. 12.8 - Prob. 5QQCh. 12.8 - Prob. 6QQCh. 12.8 - Prob. 7QQCh. 12.9 - Prob. 1QQCh. 12.9 - Prob. 2QQCh. 12.10 - Prob. 1QQCh. 12.10 - Prob. 2QQCh. 12.11 - Prob. 1QQCh. 12.11 - Prob. 2QQCh. 12.11 - Prob. 3QQCh. 12.12 - Prob. 1QQCh. 12.12 - Prob. 2QQCh. 12.12 - Prob. 3QQCh. 12.13 - Prob. 1QQCh. 12.13 - Prob. 2QQCh. 12.13 - Prob. 3QQCh. 12.14 - Prob. 1QQCh. 12.14 - Prob. 2QQCh. 12.14 - Prob. 3QQCh. 12.15 - Prob. 1QQCh. 12.15 - Prob. 2QQCh. 12.16 - Prob. 1QQCh. 12.16 - Prob. 2QQCh. 12.16 - Prob. 3QQCh. 12.17 - Prob. 1QQCh. 12.17 - Prob. 2QQCh. 12.17 - Prob. 3QQCh. 12.17 - Prob. 4QQCh. 12.18 - Prob. 1QQCh. 12.18 - Prob. 2QQCh. 12.18 - Prob. 3QQCh. 12.18 - Prob. 4QQCh. 12 - Prob. 12.1EPCh. 12 - Prob. 12.2EPCh. 12 - Prob. 12.3EPCh. 12 - Prob. 12.4EPCh. 12 - Indicate whether each of the following situations...Ch. 12 - Indicate whether each of the following situations...Ch. 12 - Prob. 12.7EPCh. 12 - Prob. 12.8EPCh. 12 - What is the difference between a saturated...Ch. 12 - Prob. 12.10EPCh. 12 - Prob. 12.11EPCh. 12 - Prob. 12.12EPCh. 12 - Prob. 12.13EPCh. 12 - Prob. 12.14EPCh. 12 - Prob. 12.15EPCh. 12 - Prob. 12.16EPCh. 12 - Prob. 12.17EPCh. 12 - Prob. 12.18EPCh. 12 - Convert the expanded structural formulas in...Ch. 12 - Prob. 12.20EPCh. 12 - Prob. 12.21EPCh. 12 - Prob. 12.22EPCh. 12 - Prob. 12.23EPCh. 12 - Prob. 12.24EPCh. 12 - Prob. 12.25EPCh. 12 - Prob. 12.26EPCh. 12 - Indicate whether each of the following would be...Ch. 12 - Indicate whether each of the following would be...Ch. 12 - Prob. 12.29EPCh. 12 - Prob. 12.30EPCh. 12 - Prob. 12.31EPCh. 12 - Prob. 12.32EPCh. 12 - Prob. 12.33EPCh. 12 - How many of the numerous seven-carbon alkane...Ch. 12 - Prob. 12.35EPCh. 12 - For each of the following pairs of structures,...Ch. 12 - Prob. 12.37EPCh. 12 - Prob. 12.38EPCh. 12 - Prob. 12.39EPCh. 12 - Prob. 12.40EPCh. 12 - Prob. 12.41EPCh. 12 - What is the name of the IUPAC prefix associated...Ch. 12 - What is the IUPAC name for each of the following...Ch. 12 - What is the IUPAC name for each of the following...Ch. 12 - Prob. 12.45EPCh. 12 - What is the chemical formula for each of the...Ch. 12 - Prob. 12.47EPCh. 12 - Prob. 12.48EPCh. 12 - Prob. 12.49EPCh. 12 - Prob. 12.50EPCh. 12 - Prob. 12.51EPCh. 12 - Prob. 12.52EPCh. 12 - Draw a condensed structural formula for each of...Ch. 12 - Draw a condensed structural formula for each of...Ch. 12 - Prob. 12.55EPCh. 12 - Prob. 12.56EPCh. 12 - Explain why the name given for each of the...Ch. 12 - Prob. 12.58EPCh. 12 - Indicate whether or not the two alkanes in each of...Ch. 12 - Prob. 12.60EPCh. 12 - How many of the 18 C8 alkane constitutional...Ch. 12 - Prob. 12.62EPCh. 12 - Prob. 12.63EPCh. 12 - Prob. 12.64EPCh. 12 - Prob. 12.65EPCh. 12 - Prob. 12.66EPCh. 12 - Do the line-angle structural formulas in each of...Ch. 12 - Do the line-angle structural formulas in each of...Ch. 12 - Convert each of the condensed structural formulas...Ch. 12 - Convert each of the condensed structural formulas...Ch. 12 - Assign an IUPAC name to each of the compounds in...Ch. 12 - Prob. 12.72EPCh. 12 - Prob. 12.73EPCh. 12 - Prob. 12.74EPCh. 12 - For each of the alkane structures in Problem...Ch. 12 - Prob. 12.76EPCh. 12 - Prob. 12.77EPCh. 12 - Prob. 12.78EPCh. 12 - Prob. 12.79EPCh. 12 - Prob. 12.80EPCh. 12 - Prob. 12.81EPCh. 12 - Prob. 12.82EPCh. 12 - Draw condensed structural formulas for the...Ch. 12 - Draw condensed structural formulas for the...Ch. 12 - To which carbon atoms in a hexane molecule can...Ch. 12 - Prob. 12.86EPCh. 12 - Prob. 12.87EPCh. 12 - Prob. 12.88EPCh. 12 - Prob. 12.89EPCh. 12 - Prob. 12.90EPCh. 12 - Prob. 12.91EPCh. 12 - Prob. 12.92EPCh. 12 - Prob. 12.93EPCh. 12 - Using the general formula for a cycloalkane,...Ch. 12 - Prob. 12.95EPCh. 12 - Prob. 12.96EPCh. 12 - Prob. 12.97EPCh. 12 - Prob. 12.98EPCh. 12 - How many secondary carbon atoms are present in...Ch. 12 - Prob. 12.100EPCh. 12 - Prob. 12.101EPCh. 12 - Assign an IUPAC name to each of the following...Ch. 12 - Prob. 12.103EPCh. 12 - What is wrong with each of the following attempts...Ch. 12 - Draw line-angle structural formulas for the...Ch. 12 - Draw line-angle structural formulas for the...Ch. 12 - Prob. 12.107EPCh. 12 - Prob. 12.108EPCh. 12 - Prob. 12.109EPCh. 12 - Prob. 12.110EPCh. 12 - Determine the number of constitutional isomers...Ch. 12 - Determine the number of constitutional isomers...Ch. 12 - Prob. 12.113EPCh. 12 - Determine whether cistrans isomerism is possible...Ch. 12 - Prob. 12.115EPCh. 12 - Prob. 12.116EPCh. 12 - Prob. 12.117EPCh. 12 - Indicate whether the members of each of the...Ch. 12 - Prob. 12.119EPCh. 12 - Prob. 12.120EPCh. 12 - Prob. 12.121EPCh. 12 - Prob. 12.122EPCh. 12 - Which member in each of the following pairs of...Ch. 12 - Prob. 12.124EPCh. 12 - Prob. 12.125EPCh. 12 - Prob. 12.126EPCh. 12 - Answer the following questions about the...Ch. 12 - Prob. 12.128EPCh. 12 - Prob. 12.129EPCh. 12 - Prob. 12.130EPCh. 12 - Prob. 12.131EPCh. 12 - Prob. 12.132EPCh. 12 - Prob. 12.133EPCh. 12 - Write structural formulas for all the possible...Ch. 12 - Assign an IUPAC name to each of the following...Ch. 12 - Assign an IUPAC name to each of the following...Ch. 12 - Prob. 12.137EPCh. 12 - Prob. 12.138EPCh. 12 - Prob. 12.139EPCh. 12 - Draw structural formulas for the following...Ch. 12 - Prob. 12.141EPCh. 12 - Prob. 12.142EPCh. 12 - Prob. 12.143EPCh. 12 - Prob. 12.144EPCh. 12 - Prob. 12.145EPCh. 12 - Prob. 12.146EPCh. 12 - Prob. 12.147EPCh. 12 - Prob. 12.148EP
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