Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 12.29P
12-29 Which of these
(a) 1-Hexene(b)2-Hexene (c) 3-Hexene(d)2-Methyl-2-hexene (e) 3-Methyl-2-hexene(f)2,3-Dimethyl-2-hexene
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(a)
• Consider E/Z stereochemistry of alkenes.
• Do not show stereochemistry in other cases.
• You do not have to explicitly draw H atoms.
Draw a structural formula for the alkene: 2-methyl-2-heptene.
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(b) Draw a structural formula for the alkene: (E)-1-chloropropene.
3-35
Each of the following descriptions applies to more than one alkane. In each case, draw and name two structures that match
the description.
(a) an isopropylheptane
(d) a trans-dihalocyclopentane
(b) a diethyldecane
(e) a (2,3-dimethylpentyl)cycloalkane
(c) a cis-diethylcyclohexane
(f) a bicyclononane
The following names are incorrect: State why each name is wrong and give the correct name
3-methyl-3-butene
cis-3-pentene
cis-2-methyl-2-pentene
Chapter 12 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 12.3 - Prob. 12.1PCh. 12.3 - Prob. 12.2PCh. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6PCh. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8PCh. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10P
Ch. 12 - Prob. 12.11PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 12.16PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 12.24PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 12.28PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 12.33PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 12.39PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 12.41PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 12.44PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 12.49PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 12.56PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 12.60PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 12.62PCh. 12 - Prob. 12.63PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 12.66PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 12.68PCh. 12 - Prob. 12.69PCh. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 12.75PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 12.81P
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- Following is the structural formula of hexabromocyclododecane. This compound was at one time used as a flame retardant in polystyrene foam insulation in buildings, but has now been banned because it had been shown to be toxic to aquatic organisms, and can disrupt thyroid hormone levels in laboratory test animals. In addition, it persists in the environment. Show how this flame retardant could be synthesized from a cycloalkatriene and write the structural formula and IUPAC name of this starting material. Br Hexabromocyclododecanearrow_forwardDraw a structural formula for an alkene with the indicated molecular formula that gives the compound shown as the major product. Note that more than one alkene may give the same compound as the major product. CHa | C5Hw + H,O CH3CCH2CH3 OH CHa I C5H10 + Br2 » CH3CHCHCH, Br Br 7H12 + HC1 oearrow_forwardDraw structural formulas for all possible carbocations formed by the reaction of each alkene with HC1. Label each carbocation as primary, secondary, or tertiary. ch3 I ch3ch,c=chch3 ch3ch2ch=chch3arrow_forward
- 13-11 Explain why the compound 1,4-dichlorobenzene does not show eis-trans isomerism.arrow_forward13-10 Account for the fact that the six-membered ring in benzene is planar but the six-membered ring in cyclohexane is not.arrow_forward12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethanearrow_forward
- 12-77 Show how to convert cyclopentene into these compounds. 1,2-Dibromocyclopentane Cyclopentanol Iodocyclopentane Cyclopentanearrow_forward/3-Ocimene, a triene found in the fragrance of cotton blossoms and several essential oils, has the 1UPAC name czs-3,7-dimethyl-l,3,6-octatriene. (Cis refers to the configuration of the double bond between carbons 3 and 4, the only double bond in this molecule about which cis-trans isomerism is possible.) Draw a structural formula for /3-ocimene.arrow_forward3. The following alkenes can be prepared by dehydration of an appropriate alcohol. Show the structure of the alcohol in each case. If the alkene can arise from dehydration of more than one alcohol, show all possibilities. CH3CH2 C=CH2 CH3CH2 a) сH-с—снCH,CHз CH3 b) c) 3-hexene d) 1,3-butadienearrow_forward
- 17- Give the common names for the following Alkenes: Ethene, Propene, 2-Methylpropene, and 2-Methyl, 1,3-butadiene.- Draw the correct structures of the following:1- 1,2-Dimethylcyclohexene2- 4,4-Dimethylcycloheptene3- Cis-2-Butene and Trans-2-Hexene4- cis-9-tricosene5- Trans-9-tricosenearrow_forwardplease do 13-18arrow_forward(1) Predict the outcome of the addition of HBr to (a) trans-2-pentene, (b) 2-methyl-2-butene, and (c) 4-methylcyclohexene. How many isomers can be formed in each case?arrow_forward
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