Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 12, Problem 12.59P
12-59 Show how to convert 1-butene to these compounds, (a) Butane(b) 2-Butanol (c) 2-Bromobutane(d) 1,2-Dibromobutane
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Draw a structural formula of an alkene that undergoes acid-catalyzed hydration to give each alcohol as the major product (more than one alkene may give each alcohol as the major product).
(a) 3-Hexanol
(b) 1-Methylcyclobutanol
(c) 2-Methyl-2-butanol
(d) 2-Propanol
3. The following alkenes can be prepared by dehydration of an appropriate alcohol. Show the
structure of the alcohol in each case. If the alkene can arise from dehydration of more than
one alcohol, show all possibilities.
CH3CH2
C=CH2
CH3CH2
a)
сH-с—снCH,CHз
CH3
b)
c)
3-hexene
d) 1,3-butadiene
[10]
10]
Q1. Do the following conversions as directed. Write the complete reaction equation.
(a) Benzaldehyde to Benzoic Acid.
(b) Propanal to 1-propanal
(c) Cyclohexanone to Cyclohexanol
(d) Acetaldehyde to Ethyl alcohol
(e) Acetone to Iso-propyl alcohol
Chapter 12 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 12.3 - Prob. 12.1PCh. 12.3 - Prob. 12.2PCh. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6PCh. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8PCh. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10P
Ch. 12 - Prob. 12.11PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 12.16PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 12.24PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 12.28PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 12.33PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 12.39PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 12.41PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 12.44PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 12.49PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 12.56PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 12.60PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 12.62PCh. 12 - Prob. 12.63PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 12.66PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 12.68PCh. 12 - Prob. 12.69PCh. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 12.75PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 12.81P
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 11-12 Why is it not accurate to describe an unbranchedalkane as a “straight-chain” hydrocarbon?arrow_forwardConsider a cyclohexane ring substituted with one methyl group and one hydroxyl group. Draw the structural formula for a compound with this composition that: Does not show cis/trans isomerism. Does show cis/trans isomerism.arrow_forwardDodecane, C12H26, is an unbranched alkane Predict the following: Will it dissolve in water? Will it dissolve in hexane? Will it burn when ignited? Is it a liquid, solid, or gas at room temperature and atmospheric pressure? Is it more or less dense than water?arrow_forward
- 12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethanearrow_forward13-11 Explain why the compound 1,4-dichlorobenzene does not show eis-trans isomerism.arrow_forwardDraw a structural formula for an alkene with the indicated molecular formula that gives the compound shown as the major product. Note that more than one alkene may give the same compound as the major product. CHa | C5Hw + H,O CH3CCH2CH3 OH CHa I C5H10 + Br2 » CH3CHCHCH, Br Br 7H12 + HC1 oearrow_forward
- Following is the structural formula of hexabromocyclododecane. This compound was at one time used as a flame retardant in polystyrene foam insulation in buildings, but has now been banned because it had been shown to be toxic to aquatic organisms, and can disrupt thyroid hormone levels in laboratory test animals. In addition, it persists in the environment. Show how this flame retardant could be synthesized from a cycloalkatriene and write the structural formula and IUPAC name of this starting material. Br Hexabromocyclododecanearrow_forwardWhich unbranched alkane (Table 11-4) has about the same boiling point as water? Calculate the molecular weight of this alkane and compare it with the molecular weight of water.arrow_forward/3-Ocimene, a triene found in the fragrance of cotton blossoms and several essential oils, has the 1UPAC name czs-3,7-dimethyl-l,3,6-octatriene. (Cis refers to the configuration of the double bond between carbons 3 and 4, the only double bond in this molecule about which cis-trans isomerism is possible.) Draw a structural formula for /3-ocimene.arrow_forward
- 11-34 What structural feature of cycloalkanes makes cis- trans isomerism in them possible?arrow_forward13-3 What is the difference in structure between a saturated and an unsaturated hydrocarbon?arrow_forward12-77 Show how to convert cyclopentene into these compounds. 1,2-Dibromocyclopentane Cyclopentanol Iodocyclopentane Cyclopentanearrow_forward
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