Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
11th Edition
ISBN: 9781305705159
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 12.77P
12-77 Show how to convert cyclopentene into these compounds.
- 1,2-Dibromocyclopentane
- Cyclopentanol
- Iodocyclopentane
- Cyclopentane
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What is the IUPAC name of the following molecule?
s
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O 6-cyclohexyl-3,4,6-trimethyl-(3Z,5E)-3,5-hexadiene
1-cyclohexyl-1,3,4-trimethyl-(1E,3Z)-1,3-hexadiene
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CH3
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Br
O 5-bromo-3,6-dimethyl-(3Z)-heptene
O 5-bromo-3,6-dimethyl-(3E)-heptene
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O 3-bromo-2,5-dimethyl-(4E)-heptene
Chapter 12 Solutions
Bundle: Introduction to General, Organic and Biochemistry, 11th + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 12.3 - Prob. 12.1PCh. 12.3 - Prob. 12.2PCh. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6PCh. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8PCh. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10P
Ch. 12 - Prob. 12.11PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 12.16PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 12.19PCh. 12 - Prob. 12.20PCh. 12 - Prob. 12.21PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 12.24PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 12.28PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 12.33PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 12.39PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 12.41PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 12.44PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 12.49PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 12.51PCh. 12 - Prob. 12.52PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 12.56PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 12.60PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 12.62PCh. 12 - Prob. 12.63PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 12.66PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 12.68PCh. 12 - Prob. 12.69PCh. 12 - Prob. 12.70PCh. 12 - Prob. 12.71PCh. 12 - Prob. 12.72PCh. 12 - Prob. 12.73PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 12.75PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 12.78PCh. 12 - Prob. 12.79PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 12.81P
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- Draw structural formulas for all possible carbocations formed by the reaction of each alkene with HC1. Label each carbocation as primary, secondary, or tertiary. ch3 I ch3ch,c=chch3 ch3ch2ch=chch3arrow_forward12-58 Show how to convert ethylene to these compounds (a) Ethane(b) Ethanol (c) Bromoethane(d) 1,2-Dibromoethane (e) Chloroethanearrow_forwardFollowing is the structural formula of hexabromocyclododecane. This compound was at one time used as a flame retardant in polystyrene foam insulation in buildings, but has now been banned because it had been shown to be toxic to aquatic organisms, and can disrupt thyroid hormone levels in laboratory test animals. In addition, it persists in the environment. Show how this flame retardant could be synthesized from a cycloalkatriene and write the structural formula and IUPAC name of this starting material. Br Hexabromocyclododecanearrow_forward
- 12-45 Draw a structural formula for the product of each reaction. 1-Methylcyclohexene + Br2 1,2-Dimethylcyclopentene + Cl2arrow_forward11-38 Why is equatorial methylcyclohexane more stable than axial methylcyclohexane?arrow_forwardName and draw structural formulas for all pos sible monochlorination products that might be formed in each reaction.arrow_forward
- 13-15 Draw structural formulas for these compounds l-Bromo-2-chloro-4-ethylbenzene 4-Bromo-l,2-dimethylbenzene 2,4,6-Trinitrotoluene 4-Phenyl-l-pentene p-Cresol (D 2,4-Dichlorophenolarrow_forward13-22 What reagents and/or catalysts are necessary to carry out each conversion? Benzene to nitrobenzene 1,4-dichlorobenzene to 2-bromo-l,4-dichlorobenzene Benzene to anilinearrow_forward13-19 Suppose you have unlabeled bottles of benzene and cyclohexene. What chemical reaction could you use to tell which bottle contains which chemical? Explain what you would do, what you would expect to see, and how you would explain your observations. Write an equation for a positive test.arrow_forward
- Show how to convert ethylene to these compounds. (a) Ethane (b) Ethanol (c) Bromoethane (d) 2-Chloroethanol (e) 1,2-Dibromoethane (f) 1,2-Ethanediol (g) Chloroethanearrow_forward12-31 Cyclodecene exists as both cis and trans isomers. Draw line-angle formulas for each isomer, showing the configuration of the double bond in each.arrow_forward14-49 Answer true or false. Today, the major carbon sources for the synthesis of methanol are coal and methane (natural gas), both nonrenewable resources. Today the major carbon sources for the synthesis of ethanol are petroleum and natural gas, both nonrenewable resources. Intermolecular acid-catalyzed dehydration of ethanol gives diethyl ether. Conversion of ethylene to ethylene glycol involves oxidation to ethylene oxide, followed by acid-catalyzed hydration (addition of water, to ethylene oxide. Ethylene glycol is soluble in water in all proportions. A major use of ethylene glycol is as automobile antifreeze.arrow_forward
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