Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 11, Problem 53Q
This chapter (together with Section 5.15) provided data for ethanol production through 2012. Use the resources of the Internet to update this information, particularly in regard to ethanol feedstocks, and the energy required to produce ethanol. Use this information to explain how bioethanol fuel meets, or does not meet, the goals of environmental sustainability and food security.
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
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18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Chapter 11 Solutions
Chemistry In Context
Ch. 11.1 - You Decide A Lifetime of Food During your...Ch. 11.2 - Prob. 11.2YTCh. 11.2 - Skill Building Unsaturated Fatty Acids a. What...Ch. 11.2 - Prob. 11.4YTCh. 11.2 - Prob. 11.5YTCh. 11.3 - Prob. 11.6YTCh. 11.3 - The following table lists the fat content for...Ch. 11.3 - a. Revisit the key ideas of green chemistry...Ch. 11.4 - Prob. 11.9YTCh. 11.5 - Prob. 11.10YT
Ch. 11.5 - Prob. 11.11YTCh. 11.5 - Prob. 11.12YTCh. 11.6 - Prob. 11.13YTCh. 11.7 - Prob. 11.14YTCh. 11.7 - Prob. 11.15YTCh. 11.7 - Prob. 11.16YTCh. 11.7 - Prob. 11.17YTCh. 11.7 - You Decide Sodium in Your Diet Compare the sodium...Ch. 11.7 - Prob. 11.19YTCh. 11.8 - Prob. 11.20YTCh. 11.8 - Prob. 11.21YTCh. 11.8 - Prob. 11.22YTCh. 11.8 - Which foods should you eat less of, and which ones...Ch. 11.9 - Prob. 11.25YTCh. 11.10 - The theme of the 2015 World Water Day was water...Ch. 11.10 - Prob. 11.27YTCh. 11.11 - Prob. 11.29YTCh. 11.11 - Prob. 11.30YTCh. 11.11 - In this section, we have described the concept of...Ch. 11.12 - Prob. 11.32YTCh. 11.12 - Prob. 11.33YTCh. 11.12 - a. Ammonia (NH3) is applied to soil in the form of...Ch. 11.12 - Prob. 11.35YTCh. 11.13 - Prob. 11.36YTCh. 11.13 - Prob. 11.37YTCh. 11.13 - Prob. 11.38YTCh. 11 - Prob. 1QCh. 11 - Prob. 2QCh. 11 - Prob. 3QCh. 11 - Prob. 4QCh. 11 - Prob. 5QCh. 11 - Prob. 6QCh. 11 - Prob. 7QCh. 11 - Prob. 8QCh. 11 - Here is the condensed structural formula for...Ch. 11 - Prob. 10QCh. 11 - Prob. 11QCh. 11 - Compare and contrast a trans fat to natural...Ch. 11 - Prob. 13QCh. 11 - Prob. 14QCh. 11 - Prob. 15QCh. 11 - Prob. 16QCh. 11 - Prob. 17QCh. 11 - Prob. 18QCh. 11 - Prob. 19QCh. 11 - Prob. 20QCh. 11 - Prob. 21QCh. 11 - Prob. 22QCh. 11 - Prob. 23QCh. 11 - Prob. 24QCh. 11 - Prob. 25QCh. 11 - One theme in this chapter is that what you eat...Ch. 11 - Prob. 27QCh. 11 - Prob. 28QCh. 11 - Prob. 29QCh. 11 - Prob. 30QCh. 11 - Explain to a friend why it is impossible to go on...Ch. 11 - Prob. 32QCh. 11 - Prob. 33QCh. 11 - Prob. 34QCh. 11 - Prob. 35QCh. 11 - Prob. 36QCh. 11 - Prob. 37QCh. 11 - Prob. 38QCh. 11 - Prob. 39QCh. 11 - Prob. 40QCh. 11 - Prob. 41QCh. 11 - Prob. 42QCh. 11 - Prob. 43QCh. 11 - Biodiesel is another example of a biofuel. Answer...Ch. 11 - Prob. 45QCh. 11 - Prob. 46QCh. 11 - Prob. 48QCh. 11 - Prob. 49QCh. 11 - Consider this structural formula for one of the...Ch. 11 - Prob. 51QCh. 11 - Prob. 52QCh. 11 - This chapter (together with Section 5.15) provided...
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- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
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