Chemistry In Context
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 11, Problem 46Q
Interpretation Introduction

Interpretation:

The primary type of fat found in avocados and the comparison of this fat to tropical oils in terms of its effect on the health has to be given.

Concept introduction:

Fatty acids are aliphatic mono-carboxylic acids that are mostly obtained from the hydrolysis of natural fats and oils. They have a general formula R(CH2)nCOOH, n is mostly an even number of carbon atoms (4 to 20) with a few exceptions that have an odd number.

Fats are triglycerides made up of one glycerol molecule and three fatty acid molecules. In fat molecules, saturated chains are packed closely together.

They are also considered as the hydrophobic substances which are soluble in the organic solvents and insoluble in water

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table  and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Chapter 11 Solutions

Chemistry In Context

Ch. 11.5 - Prob. 11.11YTCh. 11.5 - Prob. 11.12YTCh. 11.6 - Prob. 11.13YTCh. 11.7 - Prob. 11.14YTCh. 11.7 - Prob. 11.15YTCh. 11.7 - Prob. 11.16YTCh. 11.7 - Prob. 11.17YTCh. 11.7 - You Decide Sodium in Your Diet Compare the sodium...Ch. 11.7 - Prob. 11.19YTCh. 11.8 - Prob. 11.20YTCh. 11.8 - Prob. 11.21YTCh. 11.8 - Prob. 11.22YTCh. 11.8 - Which foods should you eat less of, and which ones...Ch. 11.9 - Prob. 11.25YTCh. 11.10 - The theme of the 2015 World Water Day was water...Ch. 11.10 - Prob. 11.27YTCh. 11.11 - Prob. 11.29YTCh. 11.11 - Prob. 11.30YTCh. 11.11 - In this section, we have described the concept of...Ch. 11.12 - Prob. 11.32YTCh. 11.12 - Prob. 11.33YTCh. 11.12 - a. Ammonia (NH3) is applied to soil in the form of...Ch. 11.12 - Prob. 11.35YTCh. 11.13 - Prob. 11.36YTCh. 11.13 - Prob. 11.37YTCh. 11.13 - Prob. 11.38YTCh. 11 - Prob. 1QCh. 11 - Prob. 2QCh. 11 - Prob. 3QCh. 11 - Prob. 4QCh. 11 - Prob. 5QCh. 11 - Prob. 6QCh. 11 - Prob. 7QCh. 11 - Prob. 8QCh. 11 - Here is the condensed structural formula for...Ch. 11 - Prob. 10QCh. 11 - Prob. 11QCh. 11 - Compare and contrast a trans fat to natural...Ch. 11 - Prob. 13QCh. 11 - Prob. 14QCh. 11 - Prob. 15QCh. 11 - Prob. 16QCh. 11 - Prob. 17QCh. 11 - Prob. 18QCh. 11 - Prob. 19QCh. 11 - Prob. 20QCh. 11 - Prob. 21QCh. 11 - Prob. 22QCh. 11 - Prob. 23QCh. 11 - Prob. 24QCh. 11 - Prob. 25QCh. 11 - One theme in this chapter is that what you eat...Ch. 11 - Prob. 27QCh. 11 - Prob. 28QCh. 11 - Prob. 29QCh. 11 - Prob. 30QCh. 11 - Explain to a friend why it is impossible to go on...Ch. 11 - Prob. 32QCh. 11 - Prob. 33QCh. 11 - Prob. 34QCh. 11 - Prob. 35QCh. 11 - Prob. 36QCh. 11 - Prob. 37QCh. 11 - Prob. 38QCh. 11 - Prob. 39QCh. 11 - Prob. 40QCh. 11 - Prob. 41QCh. 11 - Prob. 42QCh. 11 - Prob. 43QCh. 11 - Biodiesel is another example of a biofuel. Answer...Ch. 11 - Prob. 45QCh. 11 - Prob. 46QCh. 11 - Prob. 48QCh. 11 - Prob. 49QCh. 11 - Consider this structural formula for one of the...Ch. 11 - Prob. 51QCh. 11 - Prob. 52QCh. 11 - This chapter (together with Section 5.15) provided...
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