(a) Interpretation: The indicated bond angle in the following compound should be predicted: Concept Introduction: The following table should be used while determining the bond around an atom. Number of groups Number of atoms Number of lone pairs Shape Bond angle 2 2 0 Linear 180 ° C 3 3 0 Trigonal planar 120 ° C 4 4 0 Tetrahedral 109.5 ° C 4 3 1 Trigonal pyramidal 109.5 ° C 4 2 2 Bent 109.5 ° C

Question

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Answer 1

Question

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

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Use VSEPR to predict bond angles about each atom of carbon, nitrogen, and oxygen in these molecules.

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Answer 2

Question

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

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Answer 3

Question

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

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Answer 4

Question

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

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Answer 5

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

Answer 6

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Answer 7

Chapter 11, Problem 27P

Interpretation Introduction

(a)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 8

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 180 °C.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The given structure is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 2

In the compound, triple bonded carbon is bonded to two other groups. If two groups surround an atom and no lone pair electron are present, the bond angle is 180 °C and shape around that carbon is linear. So, angle (1) represents 180 °C . Angle (2) also is also 180 °C as two groups surround the triple bonded carbon atom.

Answer 13

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Answer 14

Interpretation Introduction

(b)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 15

Expert Solution

Answer to Problem 27P

Angle (1) and (2) both measures 120 °C.

Answer 16

Expert Solution

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Explanation of Solution

The compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 4

In the compound, three groups (hydrogen, carbon and chlorine) surround the double bonded carbon atom. And if three groups present surrounding an atom, the bond angle will be 120 °C . Hence, angle (1) and (2) both measures 120 °C.

Answer 20

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

Answer 21

Interpretation Introduction

(c)

Interpretation:

The indicated bond angle in the following compound should be predicted:

Concept Introduction:

The following table should be used while determining the bond angle around an atom.

Number of groups Number of atoms Number of lone pairs Shape Bond angle
2 2 0 Linear
180 °C
3 3 0 Trigonal planar
120 °C
4 4 0 Tetrahedral
109.5 °C
4 3 1 Trigonal pyramidal
109.5 °C
4 2 2 Bent
109.5 °C

Answer 22

Expert Solution

Answer to Problem 27P

Angle (1) and angle (2) both measures 109.5 °C.

Answer 23

Expert Solution

Answer 24

Expert Solution

Answer 25

Expert Solution

Answer 26

Explanation of Solution

Given compound is as follows:

CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY, Chapter 11, Problem 27P , additional homework tip 6

The carbon atom in the compound is surrounded by four groups (two hydrogen, one carbon and one chlorine). So, the angle between the bonds is 109.5 °C . Hence, angle (1) and (2) both measures 109.5 °C.

Answer 27

Ch. 11.1 - Prob. 11.1P Ch. 11.2 - Fill in all H's and lone pairs in each compound.Ch. 11.3 - Prob. 11.2PP Ch. 11.3 - Prob. 11.2P Ch. 11.3 - Prob. 11.3P Ch. 11.3 - Prob. 11.3PP Ch. 11.3 - How many lone pairs are present in lidocaine, the...Ch. 11.4 - Convert each compound to a condensed formula.Ch. 11.4 - Convert each condensed formula to a complete...Ch. 11.4 - Convert each skeletal structure to a complete...

Concept explainers

Answer to Problem 27P

Explanation of Solution

Answer to Problem 27P

Explanation of Solution

Answer to Problem 27P

Explanation of Solution

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Chapter 11 Solutions

Number of groups	Number of atoms	Number of lone pairs	Shape	Bond angle
2	2	0	Linear	180 °C
3	3	0	Trigonal planar	120 °C
4	4	0	Tetrahedral	109.5 °C
4	3	1	Trigonal pyramidal	109.5 °C
4	2	2	Bent	109.5 °C