Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
Question
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Chapter 11, Problem 11.55E
Interpretation Introduction

(a)

Interpretation:

The energy of the given 3-D rotational wavefunction is to be calculated.

Concept introduction:

The energy for the 3-D rotational motion is given by,

E=l(l+1)22I

The energy of the particle depends on the moment of inertia, quantum number and Planck’s constant. The total energy is quantized.

Interpretation Introduction

(b)

Interpretation:

Total angular momentum of the given 3-D rotational wavefunction is to be calculated.

Concept introduction:

The total angular momentum for the 3-Dimensional system is given by,

L=l(l+1)

The total angular momentum does not depend on the mass of the particle, radius of the rotation and also the magnetic quantum number.

Interpretation Introduction

(c)

Interpretation:

The z-component of the total angular momentum of the given 3-D rotational wavefunction is to be calculated.

Concept introduction:

The z-component of the three dimensional angular momentum that has components in x, y and z direction is quantized. Its value depends on the magnetic quantum number and it is given by,

L^z=ml

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Chapter 11 Solutions

Physical Chemistry

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