Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 11, Problem 11.44E

(a) Using the expression for the energy of a 2-D rigid rotor, construct the expression for the energy difference between two adjacent levels, E ( m + 1 ) E ( m ) . (b) For HCl , E ( 1 ) E ( 0 ) = 20.7 cm 1 . Calculate E ( 2 ) = E ( 1 ) , assuming HCl acts as a 2-D rigid rotor. (c) This energy difference is determined experimentally as 41.4 cm 1 . How good would you say a 2-D model is for this system?

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Chapter 11 Solutions

Physical Chemistry

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