Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 11, Problem 11.17E
Interpretation Introduction

Interpretation:

The validation of the expression E=3/2hv by the substitution of the Ψ1 into the complete Hamiltonian operator of an ideal harmonic oscillator is to be shown.

Concept introduction:

The Schrödinger equation for one-dimensional harmonic oscillator is,

d2Ψdx2+(2mE2α2x2)Ψ=0

Where,

m is the mass of the body.

Ψ is the wavefunction of harmonic oscillator.

E is the energy of harmonic oscillator.

has the value h2π

• The value of constant α=2πvm

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Chapter 11 Solutions

Physical Chemistry

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