Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
Question
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Chapter 10, Problem 10.13P
Interpretation Introduction

(a)

Interpretation:

The structure of the alkyl halide product of the reaction 1-propanol+HBr is to be drawn

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(b)

Interpretation:

The structure of the alkyl halide product of the reaction HOCH2CH2CH2OH+ excess HIheat is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(c)

Interpretation:

The structure of the alkyl halide product expected in the reaction of 3, 3-dimethylbutan-2-ol and excess HBr is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

Interpretation Introduction

(d)

Interpretation:

The structure of the alkyl halide product expected in the reaction of 2, 2-dimethylpropan-1-ol and hydrochloric acid is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the incoming nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular single step reaction in which the addition of incoming nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps.

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22.7 Predict the monoalkylated products of the following reactions with benzene. (a) AlCl3 Ya (b) AlCl3 (c) H3PO4 (d) 22.8 Think-Pair-Share AICI3 The reaction below is a common electrophilic aromatic substitution. SO3 H₂SO4 SO₂H (a) Draw the reaction mechanism for this reaction using HSO,+ as the electrophile. (b) Sketch the reaction coordinate diagram, where the product is lower in energy than the starting reactant. (c) Which step in the reaction mechanism is highest in energy? Explain. (d) Which of the following reaction conditions could be used in an electrophilic aro- matic substitution with benzene to provide substituted phenyl derivatives? (i) AICI3 HNO3 H₂SO4 K2Cr2O7 (iii) H₂SO4 (iv) H₂PO₁
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